Facile synthesis of Ni-ZIF-8 with improved photodegradation performance for methylene blue

A series of bimetallic metal-organic frameworks (MOFs) photocatalysts had been successfully synthesized by doping nickel (Ni) into zeolitic imidazolate framework-8 (ZIF-8) for enhanced photodegradation of methylene blue (MB). Optical characterization revealed that the Ni-ZIF-8 composites possessed a...

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Main Authors: Liyana Labiba Zulfa, Alvin Romadhoni Putra Hidayat, Wahyu Prasetyo Utomo, Riki Subagyo, Etty Nurlia Kusumawati, Yuly Kusumawati, Djoko Hartanto, Widyastuti Widyastuti, Ratna Ediati
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Case Studies in Chemical and Environmental Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666016424002226
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Summary:A series of bimetallic metal-organic frameworks (MOFs) photocatalysts had been successfully synthesized by doping nickel (Ni) into zeolitic imidazolate framework-8 (ZIF-8) for enhanced photodegradation of methylene blue (MB). Optical characterization revealed that the Ni-ZIF-8 composites possessed a narrower bandgap and lower recombination rate of charge carriers than pristine ZIF-8. The Ni(20)-ZIF-8 composite showed the highest MB photodegradation efficiency of up to 93.22 % in 150 min, with the use of 30 mg photocatalyst, 50 mL of 30 mg/L MB solution, and a neutral pH. The scavenger test clearly proved that h+ and •OH were the main active species.
ISSN:2666-0164