Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper

As the density of electronic packaging continues to rise, traditional soldering techniques encounter significant challenges, leading to copper–copper direct bonding as a new high-density connection method. The high melting point of copper presents difficulties for direct diffusion bonding under stan...

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Main Authors: Jingyan Li, Zixian Song, Zhichao Liu, Xianli Xie, Penghui Guan, Yiying Zhu
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/1/476
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author Jingyan Li
Zixian Song
Zhichao Liu
Xianli Xie
Penghui Guan
Yiying Zhu
author_facet Jingyan Li
Zixian Song
Zhichao Liu
Xianli Xie
Penghui Guan
Yiying Zhu
author_sort Jingyan Li
collection DOAJ
description As the density of electronic packaging continues to rise, traditional soldering techniques encounter significant challenges, leading to copper–copper direct bonding as a new high-density connection method. The high melting point of copper presents difficulties for direct diffusion bonding under standard conditions, thus making low-temperature copper–copper bonding a focal point of research. In this study, we examine the sintering process at various temperatures by constructing models with multiple nanoparticles and sintering them under different conditions. Our findings indicate that 600 K is a crucial temperature for direct copper–copper sintering. Below this threshold, sintering predominantly depends on structural adjustments driven by residual stresses and particle contact. Conversely, at temperatures of 600 K and above, the activation of rapid surface atomic motion enables further structural adjustments between nanoparticles, leading to a marked decrease in porosity. Mechanical testing of the sintered samples corroborated the structural changes at different temperatures, demonstrating that the surface dynamic motion of atoms inherent in low-temperature sintering mechanisms significantly affects the mechanical properties of nanomaterials. These findings have important implications for developing high-performance materials that align with the evolving requirements of modern electronic devices.
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issn 2076-3417
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publishDate 2025-01-01
publisher MDPI AG
record_format Article
series Applied Sciences
spelling doaj-art-e94bc68aa55d4c1c99bc0fe6ad6a16812025-01-10T13:15:41ZengMDPI AGApplied Sciences2076-34172025-01-0115147610.3390/app15010476Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale CopperJingyan Li0Zixian Song1Zhichao Liu2Xianli Xie3Penghui Guan4Yiying Zhu5State Key Laboratory of Intelligent Vehicle Safety Technology, Chongqing 400023, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaState Key Laboratory of Intelligent Vehicle Safety Technology, Chongqing 400023, ChinaState Key Laboratory of Intelligent Vehicle Safety Technology, Chongqing 400023, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaAs the density of electronic packaging continues to rise, traditional soldering techniques encounter significant challenges, leading to copper–copper direct bonding as a new high-density connection method. The high melting point of copper presents difficulties for direct diffusion bonding under standard conditions, thus making low-temperature copper–copper bonding a focal point of research. In this study, we examine the sintering process at various temperatures by constructing models with multiple nanoparticles and sintering them under different conditions. Our findings indicate that 600 K is a crucial temperature for direct copper–copper sintering. Below this threshold, sintering predominantly depends on structural adjustments driven by residual stresses and particle contact. Conversely, at temperatures of 600 K and above, the activation of rapid surface atomic motion enables further structural adjustments between nanoparticles, leading to a marked decrease in porosity. Mechanical testing of the sintered samples corroborated the structural changes at different temperatures, demonstrating that the surface dynamic motion of atoms inherent in low-temperature sintering mechanisms significantly affects the mechanical properties of nanomaterials. These findings have important implications for developing high-performance materials that align with the evolving requirements of modern electronic devices.https://www.mdpi.com/2076-3417/15/1/476low-temperature sinteringnanoparticlesurface atomic motionmolecular dynamic simulation
spellingShingle Jingyan Li
Zixian Song
Zhichao Liu
Xianli Xie
Penghui Guan
Yiying Zhu
Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper
Applied Sciences
low-temperature sintering
nanoparticle
surface atomic motion
molecular dynamic simulation
title Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper
title_full Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper
title_fullStr Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper
title_full_unstemmed Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper
title_short Exploring Surface-Driven Mechanisms for Low-Temperature Sintering of Nanoscale Copper
title_sort exploring surface driven mechanisms for low temperature sintering of nanoscale copper
topic low-temperature sintering
nanoparticle
surface atomic motion
molecular dynamic simulation
url https://www.mdpi.com/2076-3417/15/1/476
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AT xianlixie exploringsurfacedrivenmechanismsforlowtemperaturesinteringofnanoscalecopper
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