Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States
The millimeter-wave rotational spectra of the ground and excited vibrational states v2 =1 and v4 =1 of the symmetric top molecule, PF3, have been analyzed again. The B0 = 7819.9907(13) MHz, DJ = 7.84984(41) kHz, DJk = -11.7644 (11) kHz, HJ = 15.678 (36) mHz, HJk = -66.46 (12) mHz and HkJ = 87.42 (15...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2009-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2009/458714 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841524580013834240 |
|---|---|
| author | Masoud Motamedi Tahere Zohrevand |
| author_facet | Masoud Motamedi Tahere Zohrevand |
| author_sort | Masoud Motamedi |
| collection | DOAJ |
| description | The millimeter-wave rotational spectra of the ground and excited vibrational states v2 =1 and v4 =1 of the symmetric top molecule, PF3, have been analyzed again. The B0 = 7819.9907(13) MHz, DJ = 7.84984(41) kHz, DJk = -11.7644 (11) kHz, HJ = 15.678 (36) mHz, HJk = -66.46 (12) mHz and HkJ = 87.42 (15) mHz have been determined for ground state. The 1=±1 series have been assigned and the rotational parameters including B4 =7823.09212(41) MHz, (q+t)4 = -29.49200(65) MHz, rt=2.9465 (13) MHz and (Cζ)4 = -3010.94684(41) MHz for v4 =1 state were determined accurately |
| format | Article |
| id | doaj-art-e8b4a8673ad042f3934200e5152dc06a |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-e8b4a8673ad042f3934200e5152dc06a2025-02-03T05:52:54ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-016384986510.1155/2009/458714Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 StatesMasoud Motamedi0Tahere Zohrevand1Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, IranDepartment of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, IranThe millimeter-wave rotational spectra of the ground and excited vibrational states v2 =1 and v4 =1 of the symmetric top molecule, PF3, have been analyzed again. The B0 = 7819.9907(13) MHz, DJ = 7.84984(41) kHz, DJk = -11.7644 (11) kHz, HJ = 15.678 (36) mHz, HJk = -66.46 (12) mHz and HkJ = 87.42 (15) mHz have been determined for ground state. The 1=±1 series have been assigned and the rotational parameters including B4 =7823.09212(41) MHz, (q+t)4 = -29.49200(65) MHz, rt=2.9465 (13) MHz and (Cζ)4 = -3010.94684(41) MHz for v4 =1 state were determined accuratelyhttp://dx.doi.org/10.1155/2009/458714 |
| spellingShingle | Masoud Motamedi Tahere Zohrevand Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States E-Journal of Chemistry |
| title | Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States |
| title_full | Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States |
| title_fullStr | Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States |
| title_full_unstemmed | Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States |
| title_short | Study of Millimeter-Wave Rotational Spectra of Phosphorus Trifluoride in Ground,v2 = 1 and v4 = 1 States |
| title_sort | study of millimeter wave rotational spectra of phosphorus trifluoride in ground v2 1 and v4 1 states |
| url | http://dx.doi.org/10.1155/2009/458714 |
| work_keys_str_mv | AT masoudmotamedi studyofmillimeterwaverotationalspectraofphosphorustrifluorideingroundv21andv41states AT taherezohrevand studyofmillimeterwaverotationalspectraofphosphorustrifluorideingroundv21andv41states |