Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein

The use of green fluorescence protein (GFP) has advanced numerous areas of life sciences. An ultra-thermostable GFP (TGP), engineered from a coral GFP, offers potential advantages over traditional jellyfish-derived GFP because of its high stability. However, owing to its later discovery, TGP lacks t...

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Main Authors: Yue Zhihao, Li Yanfang, Cai Hongmin, Yao Hebang, Li Dianfan, Ni Aimin, Li Tingting
Format: Article
Language:English
Published: China Science Publishing & Media Ltd. 2024-12-01
Series:Acta Biochimica et Biophysica Sinica
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Online Access:https://www.sciengine.com/doi/10.3724/abbs.2024233
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author Yue Zhihao
Li Yanfang
Cai Hongmin
Yao Hebang
Li Dianfan
Ni Aimin
Li Tingting
author_facet Yue Zhihao
Li Yanfang
Cai Hongmin
Yao Hebang
Li Dianfan
Ni Aimin
Li Tingting
author_sort Yue Zhihao
collection DOAJ
description The use of green fluorescence protein (GFP) has advanced numerous areas of life sciences. An ultra-thermostable GFP (TGP), engineered from a coral GFP, offers potential advantages over traditional jellyfish-derived GFP because of its high stability. However, owing to its later discovery, TGP lacks the extensive toolsets available for GFP, such as heavy chain-only antibody binders known as nanobodies. In this study, we report the crystal structure of TGP in complex with Sb92, a synthetic nanobody identified from a previous in vitro screening, revealing Sb92’s precise three-dimensional epitope. This structural insight, alongside the previously characterized Sb44-TGP complex, allows us to rationally design disulfide bonds between the antigen and the antibody for tighter interactions. Using biochemical analysis, we identify two bridged complexes (TGP A18C-Sb44 V100C and TGP E118C-Sb92 S57C), with the TGP-Sb92 disulfide pair showing high resistance to reducing agents. Our study expands the toolkit available for TGP and should encourage its wider applications.
format Article
id doaj-art-e7c7cb2fdf354b5896ca6d3e93c78f81
institution Kabale University
issn 1672-9145
language English
publishDate 2024-12-01
publisher China Science Publishing & Media Ltd.
record_format Article
series Acta Biochimica et Biophysica Sinica
spelling doaj-art-e7c7cb2fdf354b5896ca6d3e93c78f812025-08-20T03:47:12ZengChina Science Publishing & Media Ltd.Acta Biochimica et Biophysica Sinica1672-91452024-12-01571363137010.3724/abbs.202423320d259ccStructure-based design of covalent nanobody binders for a thermostable green fluorescence proteinYue Zhihao0Li Yanfang1Cai Hongmin2Yao Hebang3Li Dianfan4Ni Aimin5Li Tingting6["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China","University of Chinese Academy of Sciences, Beijing 100049, China"]["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China"]["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China","State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201210, China"]["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China","School of Life Science and Technology, ShanghaiTech University, Shanghai 201210, China"]["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China"]["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China"]["Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai 200031, China"]The use of green fluorescence protein (GFP) has advanced numerous areas of life sciences. An ultra-thermostable GFP (TGP), engineered from a coral GFP, offers potential advantages over traditional jellyfish-derived GFP because of its high stability. However, owing to its later discovery, TGP lacks the extensive toolsets available for GFP, such as heavy chain-only antibody binders known as nanobodies. In this study, we report the crystal structure of TGP in complex with Sb92, a synthetic nanobody identified from a previous in vitro screening, revealing Sb92’s precise three-dimensional epitope. This structural insight, alongside the previously characterized Sb44-TGP complex, allows us to rationally design disulfide bonds between the antigen and the antibody for tighter interactions. Using biochemical analysis, we identify two bridged complexes (TGP A18C-Sb44 V100C and TGP E118C-Sb92 S57C), with the TGP-Sb92 disulfide pair showing high resistance to reducing agents. Our study expands the toolkit available for TGP and should encourage its wider applications.https://www.sciengine.com/doi/10.3724/abbs.2024233disulfide engineeringrational designsynthetic nanobodythermostable green fluorescence protein
spellingShingle Yue Zhihao
Li Yanfang
Cai Hongmin
Yao Hebang
Li Dianfan
Ni Aimin
Li Tingting
Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein
Acta Biochimica et Biophysica Sinica
disulfide engineering
rational design
synthetic nanobody
thermostable green fluorescence protein
title Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein
title_full Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein
title_fullStr Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein
title_full_unstemmed Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein
title_short Structure-based design of covalent nanobody binders for a thermostable green fluorescence protein
title_sort structure based design of covalent nanobody binders for a thermostable green fluorescence protein
topic disulfide engineering
rational design
synthetic nanobody
thermostable green fluorescence protein
url https://www.sciengine.com/doi/10.3724/abbs.2024233
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AT caihongmin structurebaseddesignofcovalentnanobodybindersforathermostablegreenfluorescenceprotein
AT yaohebang structurebaseddesignofcovalentnanobodybindersforathermostablegreenfluorescenceprotein
AT lidianfan structurebaseddesignofcovalentnanobodybindersforathermostablegreenfluorescenceprotein
AT niaimin structurebaseddesignofcovalentnanobodybindersforathermostablegreenfluorescenceprotein
AT litingting structurebaseddesignofcovalentnanobodybindersforathermostablegreenfluorescenceprotein