3-(2-Hydroxyethyl)-1-(4-nitrophenyl)-1H-benzo[d]imidazol-3-ium bromide
The cation of the title salt, C15H14N3O3+·Br−, has a dihedral angle of 24.26 (6)° between its fused imidazole and 4-nitrophenyl rings and the N—C—C—O torsion angle associated with the hydroxyethyl substituent is 60.15 (17)°. In the crystal, the bromide ions act as double acceptors for hydrogen bonds...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2024-12-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2414314624011684 |
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| Summary: | The cation of the title salt, C15H14N3O3+·Br−, has a dihedral angle of 24.26 (6)° between its fused imidazole and 4-nitrophenyl rings and the N—C—C—O torsion angle associated with the hydroxyethyl substituent is 60.15 (17)°. In the crystal, the bromide ions act as double acceptors for hydrogen bonds from a hydroxyl group (O—H...Br) and a fused imidazolium moiety (C—H...Br). Additionally, C—H...O hydrogen bonds between the phenyl group and hydroxyl oxygen atom create a two-dimensional supramolecular network extending diagonally in the crystallographic bc plane. |
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| ISSN: | 2414-3146 |