Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries
Abstract Amorphous FePO4 (AFP) is a promising cathode material for lithium‐ion and sodium‐ion batteries (LIBs & SIBs) due to its stability, high theoretical capacity, and cost‐effective processing. However, challenges such as low electronic conductivity and volumetric changes seriously hinder it...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2024-12-01
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| Series: | ChemElectroChem |
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| Online Access: | https://doi.org/10.1002/celc.202400484 |
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| author | Peng Tang John Prochest Kachenje Xiaoping Qin Huihui Li Xiangdong Zeng Haiyang Tian Wei Cao Ying Zhou Di Heng Shishi Yuan Xun Jia Xiaolong Zhang Xiaoyu Zhao |
| author_facet | Peng Tang John Prochest Kachenje Xiaoping Qin Huihui Li Xiangdong Zeng Haiyang Tian Wei Cao Ying Zhou Di Heng Shishi Yuan Xun Jia Xiaolong Zhang Xiaoyu Zhao |
| author_sort | Peng Tang |
| collection | DOAJ |
| description | Abstract Amorphous FePO4 (AFP) is a promising cathode material for lithium‐ion and sodium‐ion batteries (LIBs & SIBs) due to its stability, high theoretical capacity, and cost‐effective processing. However, challenges such as low electronic conductivity and volumetric changes seriously hinder its practical application. To overcome these hurdles, core‐shell structure synthesis emerges as a useful solution. In this work, we for the first time made this comprehensive review on the progresses of core‐shell amorphous FePO4 (CS‐AFP). This review summarizes 1) various synthesis methods such as template method, microemulsion method, and other methods, 2) characterization techniques, and 3) their involvement in improving electrochemical performance in LIBs and SIBs. In terms of further understanding the underlying mechanisms of advancing electrochemical performance of CS‐AFP, the future perspective on two main aspects were insighted: (i) in situ characterization and (ii) novel designs of materials and structure for CS‐AFP. |
| format | Article |
| id | doaj-art-e1ab5b6a25b1401b9a2a52ec47125483 |
| institution | Kabale University |
| issn | 2196-0216 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemElectroChem |
| spelling | doaj-art-e1ab5b6a25b1401b9a2a52ec471254832024-12-02T10:01:24ZengWiley-VCHChemElectroChem2196-02162024-12-011123n/an/a10.1002/celc.202400484Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion BatteriesPeng Tang0John Prochest Kachenje1Xiaoping Qin2Huihui Li3Xiangdong Zeng4Haiyang Tian5Wei Cao6Ying Zhou7Di Heng8Shishi Yuan9Xun Jia10Xiaolong Zhang11Xiaoyu Zhao12School of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaCollege of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu, Sichuan 610059 PR ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaSchool of Chemical Engineering Sichuan University of Science and Engineering Zigong, Sichuan 643000 ChinaTianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-Utilization Tianjin University of Science and Technology Tianjin 300457 ChinaAbstract Amorphous FePO4 (AFP) is a promising cathode material for lithium‐ion and sodium‐ion batteries (LIBs & SIBs) due to its stability, high theoretical capacity, and cost‐effective processing. However, challenges such as low electronic conductivity and volumetric changes seriously hinder its practical application. To overcome these hurdles, core‐shell structure synthesis emerges as a useful solution. In this work, we for the first time made this comprehensive review on the progresses of core‐shell amorphous FePO4 (CS‐AFP). This review summarizes 1) various synthesis methods such as template method, microemulsion method, and other methods, 2) characterization techniques, and 3) their involvement in improving electrochemical performance in LIBs and SIBs. In terms of further understanding the underlying mechanisms of advancing electrochemical performance of CS‐AFP, the future perspective on two main aspects were insighted: (i) in situ characterization and (ii) novel designs of materials and structure for CS‐AFP.https://doi.org/10.1002/celc.202400484Amorphous FePO4Core-shell structureLithium-ion batteriesSodium-ion batteries |
| spellingShingle | Peng Tang John Prochest Kachenje Xiaoping Qin Huihui Li Xiangdong Zeng Haiyang Tian Wei Cao Ying Zhou Di Heng Shishi Yuan Xun Jia Xiaolong Zhang Xiaoyu Zhao Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries ChemElectroChem Amorphous FePO4 Core-shell structure Lithium-ion batteries Sodium-ion batteries |
| title | Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries |
| title_full | Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries |
| title_fullStr | Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries |
| title_full_unstemmed | Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries |
| title_short | Core‐Shell Amorphous FePO4 as Cathode Material for Lithium‐Ion and Sodium‐Ion Batteries |
| title_sort | core shell amorphous fepo4 as cathode material for lithium ion and sodium ion batteries |
| topic | Amorphous FePO4 Core-shell structure Lithium-ion batteries Sodium-ion batteries |
| url | https://doi.org/10.1002/celc.202400484 |
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