One-Step Fabrication Process of Silica–Titania Superhydrophobic UV-Blocking Thin Coatings onto Polymeric Films
Developing a durable multifunctional superhydrophobic coating on polymeric films that can be industrially scalable is a challenge in the field of surface engineering. This article presents a novel method for a scalable technology using a simple single-step fabrication of a superhydrophobic coating o...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2024-12-01
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| Series: | Biomimetics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2313-7673/9/12/756 |
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| Summary: | Developing a durable multifunctional superhydrophobic coating on polymeric films that can be industrially scalable is a challenge in the field of surface engineering. This article presents a novel method for a scalable technology using a simple single-step fabrication of a superhydrophobic coating on polymeric films that exhibits excellent water-repelling and UV-blocking properties, along with impressive wear resistance and chemical robustness. A mixture of titanium precursors, tetraethylorthosilicate (TEOS), hydrophobic silanes and silica nano/micro-particles is polymerized directly on a corona-treated polymeric film which reacts with the surface via siloxane chemistry. The mixture is then spread on polymeric films using a Mayer rod, which eliminates the need for expensive equipment or multistep processes. The incorporation of silica nanoparticles along with titanium precursor and TEOS results in the formation of a silica–titania network around the silica nanoparticles. This chemically binds them to the activated surface, forming a unique dual-scale surface morphology depending on the size of the silica nanoparticles used in the coating mixture. The coated films were shown to be superhydrophobic with a high water contact angle of over 180° and a rolling angle of 0°. This is due to the combination of dual-scale micro/nano roughness with fluorinated hydrocarbons that lowered the surface free energy. The coatings exhibited excellent chemical and mechanical durability, as well as UV-blocking capabilities. The results show that the coatings remain superhydrophobic even after a sandpaper abrasion test under a pressure of 2.5 kPa for a distance of 30 m. |
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| ISSN: | 2313-7673 |