Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign

<p>The variability of ozone vertical profiles in the Paris area is analyzed using 21 d of lidar monitoring of the lower-troposphere ozone vertical profiles and planetary boundary layer (PBL) vertical structure evolution in summer 2022. Characterization of the pollution regional transport is ba...

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Main Authors: G. Ancellet, C. Viatte, A. Boynard, F. Ravetta, J. Pelon, C. Cailteau-Fischbach, P. Genau, J. Capo, A. Roy, P. Nédélec
Format: Article
Language:English
Published: Copernicus Publications 2024-11-01
Series:Atmospheric Chemistry and Physics
Online Access:https://acp.copernicus.org/articles/24/12963/2024/acp-24-12963-2024.pdf
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author G. Ancellet
C. Viatte
A. Boynard
A. Boynard
F. Ravetta
J. Pelon
C. Cailteau-Fischbach
P. Genau
J. Capo
A. Roy
P. Nédélec
author_facet G. Ancellet
C. Viatte
A. Boynard
A. Boynard
F. Ravetta
J. Pelon
C. Cailteau-Fischbach
P. Genau
J. Capo
A. Roy
P. Nédélec
author_sort G. Ancellet
collection DOAJ
description <p>The variability of ozone vertical profiles in the Paris area is analyzed using 21 d of lidar monitoring of the lower-troposphere ozone vertical profiles and planetary boundary layer (PBL) vertical structure evolution in summer 2022. Characterization of the pollution regional transport is based on daily ozone analysis of the Copernicus Atmospheric Service (CAMS) ensemble model and on backward trajectories. The CAMS simulations of the ozone plume between the surface and 3 km are consistent with the ozone measurements. Comparisons with the tropospheric ozone column retrieved by satellite observations of the Infrared Atmospheric Sounding Interferometer (IASI) show that IASI observations can capture the day-to-day variability of the 0–3 km ozone column only when the maximum altitude of the ozone plume is higher than 2 km.</p> <p>The lidar ozone vertical structure above the city center is also in good agreement with the PBL growth during the day and with the formation of the residual layer during the night. The analysis of four ozone pollution events shows that the thickness of the PBL during the day and the advection of regional-scale plumes above the PBL can significantly change the ozone concentrations above Paris. Advection of ozone-poor concentrations in the free troposphere during a Saharan dust event is able to mitigate ozone photochemical production. On the other hand, the advection of a pollution plume from continental Europe with high ozone concentrations <span class="inline-formula">&gt;</span> 140 <span class="inline-formula">µ</span>g m<span class="inline-formula"><sup>−3</sup></span> maintained high concentrations in the surface layer despite a temperature decrease and cloud cover development.</p>
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spelling doaj-art-d917d67edf13484aa60e726fb80f46c02024-11-25T10:16:24ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242024-11-0124129631298310.5194/acp-24-12963-2024Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaignG. Ancellet0C. Viatte1A. Boynard2A. Boynard3F. Ravetta4J. Pelon5C. Cailteau-Fischbach6P. Genau7J. Capo8A. Roy9P. Nédélec10LATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceLATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceLATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceSPASCIA, Ramonville-Saint-Agne, 31520, France​​​​​​​LATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceLATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceLATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceLATMOS, Sorbonne Université, Université Versailles St-Quentin, CNRS/INSU, Paris, FranceCNRM, Université de Toulouse, Météo-France, CNRS, Toulouse, FranceCNRM, Université de Toulouse, Météo-France, CNRS, Toulouse, FranceLaboratoire d’Aérologie, CNRS and Université Toulouse III, Paul Sabatier, Toulouse, France<p>The variability of ozone vertical profiles in the Paris area is analyzed using 21 d of lidar monitoring of the lower-troposphere ozone vertical profiles and planetary boundary layer (PBL) vertical structure evolution in summer 2022. Characterization of the pollution regional transport is based on daily ozone analysis of the Copernicus Atmospheric Service (CAMS) ensemble model and on backward trajectories. The CAMS simulations of the ozone plume between the surface and 3 km are consistent with the ozone measurements. Comparisons with the tropospheric ozone column retrieved by satellite observations of the Infrared Atmospheric Sounding Interferometer (IASI) show that IASI observations can capture the day-to-day variability of the 0–3 km ozone column only when the maximum altitude of the ozone plume is higher than 2 km.</p> <p>The lidar ozone vertical structure above the city center is also in good agreement with the PBL growth during the day and with the formation of the residual layer during the night. The analysis of four ozone pollution events shows that the thickness of the PBL during the day and the advection of regional-scale plumes above the PBL can significantly change the ozone concentrations above Paris. Advection of ozone-poor concentrations in the free troposphere during a Saharan dust event is able to mitigate ozone photochemical production. On the other hand, the advection of a pollution plume from continental Europe with high ozone concentrations <span class="inline-formula">&gt;</span> 140 <span class="inline-formula">µ</span>g m<span class="inline-formula"><sup>−3</sup></span> maintained high concentrations in the surface layer despite a temperature decrease and cloud cover development.</p>https://acp.copernicus.org/articles/24/12963/2024/acp-24-12963-2024.pdf
spellingShingle G. Ancellet
C. Viatte
A. Boynard
A. Boynard
F. Ravetta
J. Pelon
C. Cailteau-Fischbach
P. Genau
J. Capo
A. Roy
P. Nédélec
Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
Atmospheric Chemistry and Physics
title Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
title_full Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
title_fullStr Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
title_full_unstemmed Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
title_short Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
title_sort analysis of the day to day variability of ozone vertical profiles in the lower troposphere during the 2022 paris across campaign
url https://acp.copernicus.org/articles/24/12963/2024/acp-24-12963-2024.pdf
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