Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review

Exopolysaccharides (EPSs) are large-molecular-weight, complex carbohydrate molecules and extracellularly secreted bio-polymers released by many microorganisms, including lactic acid bacteria (LAB). LAB are well known for their ability to produce a wide range of EPSs, which has received major attenti...

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Main Authors: Manoj Kumar Yadav, Ji Hoon Song, Robie Vasquez, Jae Seung Lee, In Ho Kim, Dae-Kyung Kang
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/13/22/3687
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author Manoj Kumar Yadav
Ji Hoon Song
Robie Vasquez
Jae Seung Lee
In Ho Kim
Dae-Kyung Kang
author_facet Manoj Kumar Yadav
Ji Hoon Song
Robie Vasquez
Jae Seung Lee
In Ho Kim
Dae-Kyung Kang
author_sort Manoj Kumar Yadav
collection DOAJ
description Exopolysaccharides (EPSs) are large-molecular-weight, complex carbohydrate molecules and extracellularly secreted bio-polymers released by many microorganisms, including lactic acid bacteria (LAB). LAB are well known for their ability to produce a wide range of EPSs, which has received major attention. LAB-EPSs have the potential to improve health, and their applications are in the food and pharmaceutical industries. Several methods have been developed and optimized in recent years for producing, extracting, purifying, and characterizing LAB-produced EPSs. The simplest method of evaluating the production of EPSs is to observe morphological features, such as ropy and mucoid appearances of colonies. Ethanol precipitation is widely used to extract the EPSs from the cell-free supernatant and is generally purified using dialysis. The most commonly used method to quantify the carbohydrate content is phenol–sulfuric acid. The structural characteristics of EPSs are identified via Fourier transform infrared, nuclear magnetic resonance, and X-ray diffraction spectroscopy. The molecular weight and composition of monosaccharides are determined through size-exclusion chromatography, thin-layer chromatography, gas chromatography, and high-performance liquid chromatography. The surface morphology of EPSs is observed via scanning electron microscopy and atomic force microscopy, whereas thermal characteristics are determined through thermogravimetry analysis, derivative thermogravimetry, and differential scanning calorimetry. In the present review, we discuss the different existing methods used for the detailed study of LAB-produced EPSs, which provide a comprehensive guide on LAB-EPS preparation, critically evaluating methods, addressing knowledge gaps and key challenges, and offering solutions to enhance reproducibility, scalability, and support for both research and industrial applications.
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spelling doaj-art-d30cc069b41f4c2880d2848058c1af1a2024-11-26T18:04:49ZengMDPI AGFoods2304-81582024-11-011322368710.3390/foods13223687Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic ReviewManoj Kumar Yadav0Ji Hoon Song1Robie Vasquez2Jae Seung Lee3In Ho Kim4Dae-Kyung Kang5Department of Animal Biotechnology, Dankook University, 119 Dandae-ro, Cheonan 31116, Republic of KoreaDepartment of Animal Biotechnology, Dankook University, 119 Dandae-ro, Cheonan 31116, Republic of KoreaDepartment of Animal Biotechnology, Dankook University, 119 Dandae-ro, Cheonan 31116, Republic of KoreaDepartment of Animal Biotechnology, Dankook University, 119 Dandae-ro, Cheonan 31116, Republic of KoreaDepartment of Animal Biotechnology, Dankook University, 119 Dandae-ro, Cheonan 31116, Republic of KoreaDepartment of Animal Biotechnology, Dankook University, 119 Dandae-ro, Cheonan 31116, Republic of KoreaExopolysaccharides (EPSs) are large-molecular-weight, complex carbohydrate molecules and extracellularly secreted bio-polymers released by many microorganisms, including lactic acid bacteria (LAB). LAB are well known for their ability to produce a wide range of EPSs, which has received major attention. LAB-EPSs have the potential to improve health, and their applications are in the food and pharmaceutical industries. Several methods have been developed and optimized in recent years for producing, extracting, purifying, and characterizing LAB-produced EPSs. The simplest method of evaluating the production of EPSs is to observe morphological features, such as ropy and mucoid appearances of colonies. Ethanol precipitation is widely used to extract the EPSs from the cell-free supernatant and is generally purified using dialysis. The most commonly used method to quantify the carbohydrate content is phenol–sulfuric acid. The structural characteristics of EPSs are identified via Fourier transform infrared, nuclear magnetic resonance, and X-ray diffraction spectroscopy. The molecular weight and composition of monosaccharides are determined through size-exclusion chromatography, thin-layer chromatography, gas chromatography, and high-performance liquid chromatography. The surface morphology of EPSs is observed via scanning electron microscopy and atomic force microscopy, whereas thermal characteristics are determined through thermogravimetry analysis, derivative thermogravimetry, and differential scanning calorimetry. In the present review, we discuss the different existing methods used for the detailed study of LAB-produced EPSs, which provide a comprehensive guide on LAB-EPS preparation, critically evaluating methods, addressing knowledge gaps and key challenges, and offering solutions to enhance reproducibility, scalability, and support for both research and industrial applications.https://www.mdpi.com/2304-8158/13/22/3687characterizationexopolysaccharideslactic acid bacteriapurificationstructure
spellingShingle Manoj Kumar Yadav
Ji Hoon Song
Robie Vasquez
Jae Seung Lee
In Ho Kim
Dae-Kyung Kang
Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review
Foods
characterization
exopolysaccharides
lactic acid bacteria
purification
structure
title Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review
title_full Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review
title_fullStr Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review
title_full_unstemmed Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review
title_short Methods for Detection, Extraction, Purification, and Characterization of Exopolysaccharides of Lactic Acid Bacteria—A Systematic Review
title_sort methods for detection extraction purification and characterization of exopolysaccharides of lactic acid bacteria a systematic review
topic characterization
exopolysaccharides
lactic acid bacteria
purification
structure
url https://www.mdpi.com/2304-8158/13/22/3687
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