Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods

Asphaltenes' solubility in crude oils is frequently affected by temperature, pressure, and oil composition changes. This could lead to the precipitation and deposition of asphaltene in various parts of the total production system, which would cause a significant economic impact. Predicting the...

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Main Authors: Ali A. Ali, Ghassan H. Abdul-Majeed
Format: Article
Language:English
Published: University of Baghdad 2025-01-01
Series:Journal of Engineering
Subjects:
Online Access:https://www.joe.uobaghdad.edu.iq/index.php/main/article/view/3452
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author Ali A. Ali
Ghassan H. Abdul-Majeed
author_facet Ali A. Ali
Ghassan H. Abdul-Majeed
author_sort Ali A. Ali
collection DOAJ
description Asphaltenes' solubility in crude oils is frequently affected by temperature, pressure, and oil composition changes. This could lead to the precipitation and deposition of asphaltene in various parts of the total production system, which would cause a significant economic impact. Predicting the conditions of asphaltene precipitation will be very useful in two cases. In the first case, without the problem, it will be useful in specifying the optimum operating conditions of oil production operations. In the second case, with the problem occurring, the prediction model will be useful in knowing the deposition areas and their sizes. This study is an extension of the first part, in which the advanced versions of Peng-Robinson (APR78 EOS) and Soave-Redlich-Kwong (ASRK EOS) cubic equations of state and cubic-plus-association equations of state (CPA EOS) were compared in predicting asphaltene precipitation conditions by using Multiflash software. The prediction was made for live crude oil (API gravity = 24˚ API) from an Iraqi oil field at different temperatures. The required data for modeling are fluid compositional analysis, PVT experiment data, and flow assurance data, which were collected from a fluid analysis report. It was noticed that the agreement in prediction was very high between the ASRK EOS and the CPA EOS for all temperature values and diverged from the APR78 EOS model at low temperatures (T = 50 and 40 ˚C). This study demonstrates the impact of selecting the appropriate model on predicting asphaltene precipitation and its influence on future predictions of the asphaltene deposition problem.
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spelling doaj-art-d25766ac6e8f4f3fa49799abd7b213d62025-01-17T10:41:14ZengUniversity of BaghdadJournal of Engineering1726-40732520-33392025-01-0131110.31026/j.eng.2025.01.03Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction MethodsAli A. Ali0Ghassan H. Abdul-Majeed1Department of Oil and Gas Engineering, University of TechnologyCollege of Engineering, University of Baghdad Asphaltenes' solubility in crude oils is frequently affected by temperature, pressure, and oil composition changes. This could lead to the precipitation and deposition of asphaltene in various parts of the total production system, which would cause a significant economic impact. Predicting the conditions of asphaltene precipitation will be very useful in two cases. In the first case, without the problem, it will be useful in specifying the optimum operating conditions of oil production operations. In the second case, with the problem occurring, the prediction model will be useful in knowing the deposition areas and their sizes. This study is an extension of the first part, in which the advanced versions of Peng-Robinson (APR78 EOS) and Soave-Redlich-Kwong (ASRK EOS) cubic equations of state and cubic-plus-association equations of state (CPA EOS) were compared in predicting asphaltene precipitation conditions by using Multiflash software. The prediction was made for live crude oil (API gravity = 24˚ API) from an Iraqi oil field at different temperatures. The required data for modeling are fluid compositional analysis, PVT experiment data, and flow assurance data, which were collected from a fluid analysis report. It was noticed that the agreement in prediction was very high between the ASRK EOS and the CPA EOS for all temperature values and diverged from the APR78 EOS model at low temperatures (T = 50 and 40 ˚C). This study demonstrates the impact of selecting the appropriate model on predicting asphaltene precipitation and its influence on future predictions of the asphaltene deposition problem. https://www.joe.uobaghdad.edu.iq/index.php/main/article/view/3452Asphaltene onset pressureAsphaltene precipitationConcentrationFlow assuranceCubic equation of state
spellingShingle Ali A. Ali
Ghassan H. Abdul-Majeed
Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods
Journal of Engineering
Asphaltene onset pressure
Asphaltene precipitation
Concentration
Flow assurance
Cubic equation of state
title Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods
title_full Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods
title_fullStr Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods
title_full_unstemmed Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods
title_short Modeling Asphaltene Precipitation-Part II: Comparative Study for Asphaltene Precipitation Curve Prediction Methods
title_sort modeling asphaltene precipitation part ii comparative study for asphaltene precipitation curve prediction methods
topic Asphaltene onset pressure
Asphaltene precipitation
Concentration
Flow assurance
Cubic equation of state
url https://www.joe.uobaghdad.edu.iq/index.php/main/article/view/3452
work_keys_str_mv AT aliaali modelingasphalteneprecipitationpartiicomparativestudyforasphalteneprecipitationcurvepredictionmethods
AT ghassanhabdulmajeed modelingasphalteneprecipitationpartiicomparativestudyforasphalteneprecipitationcurvepredictionmethods