Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage

Phthalates are widely used plasticizers that can leach from consumer products and pose potential health risks, particularly to infants whose developing systems are vulnerable to environmental toxicants. While various exposure pathways have been identified, the contribution of dermal absorption from...

Full description

Saved in:
Bibliographic Details
Main Authors: Xi Lai, Jiang Zhu, Yangyang Liu, Shengtao Ma, Meiqing Lin, Yan Hu, Jingjing Liang, Yanyan Song, Wenyan Li, Tianxin Zhao
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Toxics
Subjects:
Online Access:https://www.mdpi.com/2305-6304/13/3/218
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850279730608078848
author Xi Lai
Jiang Zhu
Yangyang Liu
Shengtao Ma
Meiqing Lin
Yan Hu
Jingjing Liang
Yanyan Song
Wenyan Li
Tianxin Zhao
author_facet Xi Lai
Jiang Zhu
Yangyang Liu
Shengtao Ma
Meiqing Lin
Yan Hu
Jingjing Liang
Yanyan Song
Wenyan Li
Tianxin Zhao
author_sort Xi Lai
collection DOAJ
description Phthalates are widely used plasticizers that can leach from consumer products and pose potential health risks, particularly to infants whose developing systems are vulnerable to environmental toxicants. While various exposure pathways have been identified, the contribution of dermal absorption from disposable diapers remains inadequately characterized. This study recruited 66 infants from Guangzhou, a representative city in southern China. Paired disposable diaper and urine samples were collected from each participant. Six phthalates in the diapers and nine metabolites in the urine were quantitatively analyzed. The predominant phthalate detected in the diapers was bis-2-ethylhexyl phthalate (DEHP, with a median concentration of 1670 ng/g, range: 678–5200 ng/g), followed by di-n-butyl phthalate (DnBP, 948 ng/g, range: 189–5980 ng/g), di-iso-butyl phthalate (DiBP, 333 ng/g, range: 16.1–4910 ng/g), and diethyl phthalate (DEP, 252 ng/g, range: 116–3350 ng/g). In urine, metabolites of DEHP (mEHP, mEHHP, and mEOHP) were the most abundant (87.1 ng/mL), followed by mnBP (metabolites of DnBP, 44.6 ng/mL), mEP (metabolites of DEP, 33.7 ng/mL), and miBP (metabolites of DiBP, 13.9 ng/mL). A positive correlation was observed between DnBP levels in diapers and mnBP levels in urine (r = 0.259, <i>p</i> = 0.035). Additionally, several urinary metabolites (miBP, mnBP, and mEP) were positively associated with a biomarker of DNA oxidative damage, 8-hydroxydeoxyguanosine (r = 0.265–0.316, <i>p</i> < 0.01). The estimated daily uptake of DEP, DiBP, DnBP, and DEHP through dermal absorption from diapers accounted for 44.9%, 19.5%, 15.1%, and 7.76% of total exposure to these phthalates, respectively. These findings suggest that dermal absorption from diapers is a significant exposure pathway for infants. Given that both the amount of exposure and the contribution of dermal uptake are higher in younger infants, further attention is warranted to understand the potential effects of transdermal phthalate exposure on infant growth and development.
format Article
id doaj-art-d1e8bb8ee5f44cd58d0b8ff3d4ddda23
institution OA Journals
issn 2305-6304
language English
publishDate 2025-03-01
publisher MDPI AG
record_format Article
series Toxics
spelling doaj-art-d1e8bb8ee5f44cd58d0b8ff3d4ddda232025-08-20T01:49:00ZengMDPI AGToxics2305-63042025-03-0113321810.3390/toxics13030218Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative DamageXi Lai0Jiang Zhu1Yangyang Liu2Shengtao Ma3Meiqing Lin4Yan Hu5Jingjing Liang6Yanyan Song7Wenyan Li8Tianxin Zhao9Department of Child Health Care, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaDepartment of Child Health Care, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaGuangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution Control, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaGuangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution Control, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaGuangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution Control, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, ChinaDepartment of Child Health Care, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaDepartment of Child Health Care, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaDepartment of Child Health Care, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaDepartment of Respiratory, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaDepartment of Urology, Guangzhou Women and Children’s Medical Center, Guangzhou Medical University, Guangdong Provincial Clinical Research Center for Child Health, Guangzhou 510623, ChinaPhthalates are widely used plasticizers that can leach from consumer products and pose potential health risks, particularly to infants whose developing systems are vulnerable to environmental toxicants. While various exposure pathways have been identified, the contribution of dermal absorption from disposable diapers remains inadequately characterized. This study recruited 66 infants from Guangzhou, a representative city in southern China. Paired disposable diaper and urine samples were collected from each participant. Six phthalates in the diapers and nine metabolites in the urine were quantitatively analyzed. The predominant phthalate detected in the diapers was bis-2-ethylhexyl phthalate (DEHP, with a median concentration of 1670 ng/g, range: 678–5200 ng/g), followed by di-n-butyl phthalate (DnBP, 948 ng/g, range: 189–5980 ng/g), di-iso-butyl phthalate (DiBP, 333 ng/g, range: 16.1–4910 ng/g), and diethyl phthalate (DEP, 252 ng/g, range: 116–3350 ng/g). In urine, metabolites of DEHP (mEHP, mEHHP, and mEOHP) were the most abundant (87.1 ng/mL), followed by mnBP (metabolites of DnBP, 44.6 ng/mL), mEP (metabolites of DEP, 33.7 ng/mL), and miBP (metabolites of DiBP, 13.9 ng/mL). A positive correlation was observed between DnBP levels in diapers and mnBP levels in urine (r = 0.259, <i>p</i> = 0.035). Additionally, several urinary metabolites (miBP, mnBP, and mEP) were positively associated with a biomarker of DNA oxidative damage, 8-hydroxydeoxyguanosine (r = 0.265–0.316, <i>p</i> < 0.01). The estimated daily uptake of DEP, DiBP, DnBP, and DEHP through dermal absorption from diapers accounted for 44.9%, 19.5%, 15.1%, and 7.76% of total exposure to these phthalates, respectively. These findings suggest that dermal absorption from diapers is a significant exposure pathway for infants. Given that both the amount of exposure and the contribution of dermal uptake are higher in younger infants, further attention is warranted to understand the potential effects of transdermal phthalate exposure on infant growth and development.https://www.mdpi.com/2305-6304/13/3/218phthalatesnewborn babiesdermal exposuredisposable baby diapers8-OHdG
spellingShingle Xi Lai
Jiang Zhu
Yangyang Liu
Shengtao Ma
Meiqing Lin
Yan Hu
Jingjing Liang
Yanyan Song
Wenyan Li
Tianxin Zhao
Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage
Toxics
phthalates
newborn babies
dermal exposure
disposable baby diapers
8-OHdG
title Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage
title_full Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage
title_fullStr Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage
title_full_unstemmed Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage
title_short Infants’ Dermal Exposure to Phthalates from Disposable Baby Diapers and Its Association with DNA Oxidative Damage
title_sort infants dermal exposure to phthalates from disposable baby diapers and its association with dna oxidative damage
topic phthalates
newborn babies
dermal exposure
disposable baby diapers
8-OHdG
url https://www.mdpi.com/2305-6304/13/3/218
work_keys_str_mv AT xilai infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT jiangzhu infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT yangyangliu infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT shengtaoma infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT meiqinglin infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT yanhu infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT jingjingliang infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT yanyansong infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT wenyanli infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage
AT tianxinzhao infantsdermalexposuretophthalatesfromdisposablebabydiapersanditsassociationwithdnaoxidativedamage