Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]]
The title compound is a germanium-based hybrid metal halide that represents a less-toxic alternative to more popular lead-based analogues in optoelectronic applications. {(2-IC2H4NH3)2[GeI4]}n is composed of infinite inorganic layers that are formed by [GeI6]4− octahedra connected in a corner-sharin...
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International Union of Crystallography
2025-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989024011800 |
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| author | Olesia I. Kucheriv Mircea-Odin Apostu Olena Prysiazhna Vadim A. Potaskalov Sergey O. Malinkin |
| author_facet | Olesia I. Kucheriv Mircea-Odin Apostu Olena Prysiazhna Vadim A. Potaskalov Sergey O. Malinkin |
| author_sort | Olesia I. Kucheriv |
| collection | DOAJ |
| description | The title compound is a germanium-based hybrid metal halide that represents a less-toxic alternative to more popular lead-based analogues in optoelectronic applications. {(2-IC2H4NH3)2[GeI4]}n is composed of infinite inorganic layers that are formed by [GeI6]4− octahedra connected in a corner-sharing manner with four equatorial I atoms. The organic (2-IC2H4NH3)+ cations interleave the inorganic layers. There are two types of 2-iodoethylammonium cations, with synclinal and antiperiplanar conformations. The organic cations interact with the inorganic layers through hydrogen bonds and I...I contacts. The crystal under investigation was twinned by a 180° rotation around [100]. |
| format | Article |
| id | doaj-art-d16b7f539896451bbf9ea690b8c7f65c |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-d16b7f539896451bbf9ea690b8c7f65c2025-01-06T09:23:11ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-01-01811343810.1107/S2056989024011800oo2009Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]]Olesia I. Kucheriv0Mircea-Odin Apostu1Olena Prysiazhna2Vadim A. Potaskalov3Sergey O. Malinkin4Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, UkraineDepartment of Chemistry, Faculty of Chemistry, Al. I. Cuza University of Iasi, Carol I Blvd. 11, Iasi 700506, RomaniaBakul Institute for Superhard Materials, National Academy of Sciences of Ukraine, Avtozavodskaya St. 2, Kyiv 04074, UkraineDepartment of General and Inorganic Chemistry, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Beresteiskyi Pr. 37, 03056 Kyiv, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, UkraineThe title compound is a germanium-based hybrid metal halide that represents a less-toxic alternative to more popular lead-based analogues in optoelectronic applications. {(2-IC2H4NH3)2[GeI4]}n is composed of infinite inorganic layers that are formed by [GeI6]4− octahedra connected in a corner-sharing manner with four equatorial I atoms. The organic (2-IC2H4NH3)+ cations interleave the inorganic layers. There are two types of 2-iodoethylammonium cations, with synclinal and antiperiplanar conformations. The organic cations interact with the inorganic layers through hydrogen bonds and I...I contacts. The crystal under investigation was twinned by a 180° rotation around [100].https://journals.iucr.org/paper?S2056989024011800crystal structurehybrid perovskitegermanium(ii)organic cation |
| spellingShingle | Olesia I. Kucheriv Mircea-Odin Apostu Olena Prysiazhna Vadim A. Potaskalov Sergey O. Malinkin Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]] Acta Crystallographica Section E: Crystallographic Communications crystal structure hybrid perovskite germanium(ii) organic cation |
| title | Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]] |
| title_full | Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]] |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]] |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]] |
| title_short | Crystal structure and Hirshfeld surface analysis of the layered hybrid metal halide poly[bis(2-iodoethylammonium) [di-μ-iodido-diiodidogermanate(II)]] |
| title_sort | crystal structure and hirshfeld surface analysis of the layered hybrid metal halide poly bis 2 iodoethylammonium di μ iodido diiodidogermanate ii |
| topic | crystal structure hybrid perovskite germanium(ii) organic cation |
| url | https://journals.iucr.org/paper?S2056989024011800 |
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