In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events

Due to the increasing number of authorized events in the European Union, it is crucial for the official laboratories to enforce market control to detect and quantify genetically modified organisms. In this study, an in-house validation of quantitative duplex ddPCR methods was performed involving MON...

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Main Authors: Daniela Verginelli, Sara Ciuffa, Katia Spinella, Davide La Rocca, Marisa Misto, Cinzia Quarchioni, Pamela Bonini, Cristiana Fusco, Lorella Peroni, Stefania Peddis, Ugo Marchesi
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/13/24/4011
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author Daniela Verginelli
Sara Ciuffa
Katia Spinella
Davide La Rocca
Marisa Misto
Cinzia Quarchioni
Pamela Bonini
Cristiana Fusco
Lorella Peroni
Stefania Peddis
Ugo Marchesi
author_facet Daniela Verginelli
Sara Ciuffa
Katia Spinella
Davide La Rocca
Marisa Misto
Cinzia Quarchioni
Pamela Bonini
Cristiana Fusco
Lorella Peroni
Stefania Peddis
Ugo Marchesi
author_sort Daniela Verginelli
collection DOAJ
description Due to the increasing number of authorized events in the European Union, it is crucial for the official laboratories to enforce market control to detect and quantify genetically modified organisms. In this study, an in-house validation of quantitative duplex ddPCR methods was performed involving MON87701, MON87769, MON89788 and CV-127-9 assays with respect to the lectin reference gene. Since the ddPCR methods provide accurate quantification, show less sensitivity to PCR inhibitors and are more suitable for multiplexing compared to the real-time PCR, the optimization of the existing assays was performed with the exception of MON87701, according to the JRC Guidance documents and technical reports. However, some concerns related to practical settings for the quantitative multiplex of ddPCR methods and their validation were encountered; therefore, a general workflow to develop and validate a ddPCR-based method is shown. The obtained data and the validation performance parameters such as specificity, cross-talk, robustness, dynamic range, linearity, the limit of quantification, trueness and precision comply with international recommendations for GMO quantification methods. The duplex ddPCR methods here investigated are equivalent in terms of performance compared to the singleplex real-time PCR methods, showing higher flexibility and cost effectiveness.
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institution Kabale University
issn 2304-8158
language English
publishDate 2024-12-01
publisher MDPI AG
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series Foods
spelling doaj-art-cfb6d82319b14b4ea25157329b921ed92024-12-27T14:26:14ZengMDPI AGFoods2304-81582024-12-011324401110.3390/foods13244011In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean EventsDaniela Verginelli0Sara Ciuffa1Katia Spinella2Davide La Rocca3Marisa Misto4Cinzia Quarchioni5Pamela Bonini6Cristiana Fusco7Lorella Peroni8Stefania Peddis9Ugo Marchesi10National Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyNational Reference Laboratory for GM Food and Feed, GMO Unit, Istituto Zooprofilattico Sperimentale del Lazio e della Toscana “Mariano Aleandri”, 00178 Rome, ItalyDue to the increasing number of authorized events in the European Union, it is crucial for the official laboratories to enforce market control to detect and quantify genetically modified organisms. In this study, an in-house validation of quantitative duplex ddPCR methods was performed involving MON87701, MON87769, MON89788 and CV-127-9 assays with respect to the lectin reference gene. Since the ddPCR methods provide accurate quantification, show less sensitivity to PCR inhibitors and are more suitable for multiplexing compared to the real-time PCR, the optimization of the existing assays was performed with the exception of MON87701, according to the JRC Guidance documents and technical reports. However, some concerns related to practical settings for the quantitative multiplex of ddPCR methods and their validation were encountered; therefore, a general workflow to develop and validate a ddPCR-based method is shown. The obtained data and the validation performance parameters such as specificity, cross-talk, robustness, dynamic range, linearity, the limit of quantification, trueness and precision comply with international recommendations for GMO quantification methods. The duplex ddPCR methods here investigated are equivalent in terms of performance compared to the singleplex real-time PCR methods, showing higher flexibility and cost effectiveness.https://www.mdpi.com/2304-8158/13/24/4011GMOvalidationddPCRsoybeanmeasurement uncertainty
spellingShingle Daniela Verginelli
Sara Ciuffa
Katia Spinella
Davide La Rocca
Marisa Misto
Cinzia Quarchioni
Pamela Bonini
Cristiana Fusco
Lorella Peroni
Stefania Peddis
Ugo Marchesi
In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events
Foods
GMO
validation
ddPCR
soybean
measurement uncertainty
title In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events
title_full In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events
title_fullStr In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events
title_full_unstemmed In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events
title_short In-House Validation of Four Duplex Droplet Digital PCR Assays to Quantify GM Soybean Events
title_sort in house validation of four duplex droplet digital pcr assays to quantify gm soybean events
topic GMO
validation
ddPCR
soybean
measurement uncertainty
url https://www.mdpi.com/2304-8158/13/24/4011
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