Facile synthesis of two-photon absorbing polymers through radical copolymerization

A two-photon absorbing polymer has been prepared through radical copolymerization of methyl acrylate and a synthesized monomer containing a two-photon absorbing chromophore (E,E,E)-1,3,5-tristyrylbenzene (1), under conventional radical polymerization conditions. The synthesized polymer was character...

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Format: Article
Language:English
Published: Budapest University of Technology and Economics 2007-08-01
Series:eXPRESS Polymer Letters
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Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0000275&mi=cd
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description A two-photon absorbing polymer has been prepared through radical copolymerization of methyl acrylate and a synthesized monomer containing a two-photon absorbing chromophore (E,E,E)-1,3,5-tristyrylbenzene (1), under conventional radical polymerization conditions. The synthesized polymer was characterized by nuclear magnetic resonance (NMR), infra-red spectroscopy (IR) and gel permeation chromatography (GPC). The linear and nonlinear optical properties were studied by measurement of UV-Vis absorption, fluorescent emission and two-photon cross-section. This synthetic strategy provided a facile approach for synthesis of photonic materials with adjustable chromophore concentration and high molecular weights.
format Article
id doaj-art-cf2076bfa3004a7fa2e643a2a374ce09
institution Kabale University
issn 1788-618X
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publishDate 2007-08-01
publisher Budapest University of Technology and Economics
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series eXPRESS Polymer Letters
spelling doaj-art-cf2076bfa3004a7fa2e643a2a374ce092025-08-20T03:57:44ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2007-08-011848248710.3144/expresspolymlett.2007.68Facile synthesis of two-photon absorbing polymers through radical copolymerizationA two-photon absorbing polymer has been prepared through radical copolymerization of methyl acrylate and a synthesized monomer containing a two-photon absorbing chromophore (E,E,E)-1,3,5-tristyrylbenzene (1), under conventional radical polymerization conditions. The synthesized polymer was characterized by nuclear magnetic resonance (NMR), infra-red spectroscopy (IR) and gel permeation chromatography (GPC). The linear and nonlinear optical properties were studied by measurement of UV-Vis absorption, fluorescent emission and two-photon cross-section. This synthetic strategy provided a facile approach for synthesis of photonic materials with adjustable chromophore concentration and high molecular weights.http://www.expresspolymlett.com/letolt.php?file=EPL-0000275&mi=cdPolymer synthesis, molecular etwo-photon absorbing polymerradical copolymerization
spellingShingle Facile synthesis of two-photon absorbing polymers through radical copolymerization
eXPRESS Polymer Letters
Polymer synthesis, molecular e
two-photon absorbing polymer
radical copolymerization
title Facile synthesis of two-photon absorbing polymers through radical copolymerization
title_full Facile synthesis of two-photon absorbing polymers through radical copolymerization
title_fullStr Facile synthesis of two-photon absorbing polymers through radical copolymerization
title_full_unstemmed Facile synthesis of two-photon absorbing polymers through radical copolymerization
title_short Facile synthesis of two-photon absorbing polymers through radical copolymerization
title_sort facile synthesis of two photon absorbing polymers through radical copolymerization
topic Polymer synthesis, molecular e
two-photon absorbing polymer
radical copolymerization
url http://www.expresspolymlett.com/letolt.php?file=EPL-0000275&mi=cd