Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents
Abstract The oxidation of 5-HMF to HMFCA is an important yet complex process, as it generates high-value chemical intermediates. Achieving this transformation efficiently requires the development of non-precious, highly active catalysts derived from renewable biomass sources. In this work, we introd...
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Nature Portfolio
2024-12-01
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| Online Access: | https://doi.org/10.1038/s41598-024-82844-3 |
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| author | Samaneh Sedigh Ashrafi Behrooz Maleki |
| author_facet | Samaneh Sedigh Ashrafi Behrooz Maleki |
| author_sort | Samaneh Sedigh Ashrafi |
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| description | Abstract The oxidation of 5-HMF to HMFCA is an important yet complex process, as it generates high-value chemical intermediates. Achieving this transformation efficiently requires the development of non-precious, highly active catalysts derived from renewable biomass sources. In this work, we introduce UoM-1 (UoM, University of Mazandaran), a novel cobalt-based metal-organic framework (Co-MOF) synthesized using a simple one-step ultrasonic irradiation method. The synthesis employed the ligand 4,4’-((1E,1’E)-((5-carboxy-1,3-phenylene)bis(azaneylylidene))bis (methaneylylidene))dibenzoic acid (H3bdda). A comprehensive suite of analytical techniques, including FT-IR, EDX, ICP, XRD, TEM, DLS, FESEM, and BET-BJH, was used to confirm the structural integrity of the synthesized material. The catalytic performance of UoM-1 was investigated for the selective conversion of HMF to HMFCA, demonstrating its effectiveness as a low-cost, accessible catalyst. To promote a more sustainable and environmentally friendly approach, the oxidation reactions were performed in deep eutectic solvents, which offer a green, low-energy alternative to traditional solvents. This study shows that the UoM-1 catalyst not only provides an economical solution but also aligns with modern green chemistry principles, making it a highly promising candidate for future catalytic applications. |
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| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2024-12-01 |
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| spelling | doaj-art-cefca8f9d4854fe98b1bbbcd19c9644b2024-12-29T12:29:19ZengNature PortfolioScientific Reports2045-23222024-12-0114111610.1038/s41598-024-82844-3Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solventsSamaneh Sedigh Ashrafi0Behrooz Maleki1Department of Organic Chemistry, Faculty of Chemistry, University of MazandaranDepartment of Organic Chemistry, Faculty of Chemistry, University of MazandaranAbstract The oxidation of 5-HMF to HMFCA is an important yet complex process, as it generates high-value chemical intermediates. Achieving this transformation efficiently requires the development of non-precious, highly active catalysts derived from renewable biomass sources. In this work, we introduce UoM-1 (UoM, University of Mazandaran), a novel cobalt-based metal-organic framework (Co-MOF) synthesized using a simple one-step ultrasonic irradiation method. The synthesis employed the ligand 4,4’-((1E,1’E)-((5-carboxy-1,3-phenylene)bis(azaneylylidene))bis (methaneylylidene))dibenzoic acid (H3bdda). A comprehensive suite of analytical techniques, including FT-IR, EDX, ICP, XRD, TEM, DLS, FESEM, and BET-BJH, was used to confirm the structural integrity of the synthesized material. The catalytic performance of UoM-1 was investigated for the selective conversion of HMF to HMFCA, demonstrating its effectiveness as a low-cost, accessible catalyst. To promote a more sustainable and environmentally friendly approach, the oxidation reactions were performed in deep eutectic solvents, which offer a green, low-energy alternative to traditional solvents. This study shows that the UoM-1 catalyst not only provides an economical solution but also aligns with modern green chemistry principles, making it a highly promising candidate for future catalytic applications.https://doi.org/10.1038/s41598-024-82844-35-HMFHMFCADeep eutectic solventsCo-MOFSchiff base |
| spellingShingle | Samaneh Sedigh Ashrafi Behrooz Maleki Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents Scientific Reports 5-HMF HMFCA Deep eutectic solvents Co-MOF Schiff base |
| title | Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents |
| title_full | Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents |
| title_fullStr | Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents |
| title_full_unstemmed | Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents |
| title_short | Catalytic conversion of biomass-derived 5-hydroxymethylfurfural to 5-hydroxymethyl-2-furancarboxylic acid using novel cobalt-based MOF in the presence of deep eutectic solvents |
| title_sort | catalytic conversion of biomass derived 5 hydroxymethylfurfural to 5 hydroxymethyl 2 furancarboxylic acid using novel cobalt based mof in the presence of deep eutectic solvents |
| topic | 5-HMF HMFCA Deep eutectic solvents Co-MOF Schiff base |
| url | https://doi.org/10.1038/s41598-024-82844-3 |
| work_keys_str_mv | AT samanehsedighashrafi catalyticconversionofbiomassderived5hydroxymethylfurfuralto5hydroxymethyl2furancarboxylicacidusingnovelcobaltbasedmofinthepresenceofdeepeutecticsolvents AT behroozmaleki catalyticconversionofbiomassderived5hydroxymethylfurfuralto5hydroxymethyl2furancarboxylicacidusingnovelcobaltbasedmofinthepresenceofdeepeutecticsolvents |