Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water

In this study, high mineral scaling propensity geothermal water was treated using a FilmTech BW30-2540 reverse osmosis (RO) membrane, integrated into a mini-pilot scale membrane test unit installed at a geothermal heating center. The study was conducted in eight cycles by monitoring membrane fouling...

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Main Authors: Aseel Zaid, Yakubu Abdullahi Jarma, Islam Rashad Ahmed Senan, Aslı Karaoğlu, Aydın Cihanoğlu, Alper Baba, Nalan Kabay
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-01-01
Series:Frontiers in Membrane Science and Technology
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Online Access:https://www.frontiersin.org/articles/10.3389/frmst.2024.1408595/full
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author Aseel Zaid
Yakubu Abdullahi Jarma
Islam Rashad Ahmed Senan
Aslı Karaoğlu
Aslı Karaoğlu
Aydın Cihanoğlu
Aydın Cihanoğlu
Alper Baba
Nalan Kabay
author_facet Aseel Zaid
Yakubu Abdullahi Jarma
Islam Rashad Ahmed Senan
Aslı Karaoğlu
Aslı Karaoğlu
Aydın Cihanoğlu
Aydın Cihanoğlu
Alper Baba
Nalan Kabay
author_sort Aseel Zaid
collection DOAJ
description In this study, high mineral scaling propensity geothermal water was treated using a FilmTech BW30-2540 reverse osmosis (RO) membrane, integrated into a mini-pilot scale membrane test unit installed at a geothermal heating center. The study was conducted in eight cycles by monitoring membrane fouling via membrane flux decline. Firstly, the geothermal water coming from the source at approximately 80°C was taken into holding tanks and allowed to reach approximately room temperature (25°C). Then, the geothermal water that reached this temperature was used in the system. The fouling degree was compared to the initial permeability of the virgin membrane. After each treatment cycle, the membrane’s permeability was evaluated both before and after acid cleaning. Permeability testing was conducted using RO permeate as the feed, under pressures ranging from 8 to 30 bar, with 2-bar increments. The geothermal water treatment was performed at a constant pressure of 15 bar, with a water recovery maintained at approximately 50%. Prior to each permeability test, the membrane underwent a 45-min wash with citric acid, followed by a rinse with RO permeate. During the first five cycles, citric acid was used at a concentration of 1000 mg/L, achieving a flux recovery of 86.6% by the fifth cycle. In the subsequent three cycles, the citric acid concentration was increased to 4000 mg/L, resulting in a flux recovery of 63.4% by the eighth cycle. The study concluded that scale formation on the membrane surface intensified as the number of cycles increased.
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spelling doaj-art-ccd8c054263a4352990e528d0beceb812025-01-08T06:12:08ZengFrontiers Media S.A.Frontiers in Membrane Science and Technology2813-10102025-01-01310.3389/frmst.2024.14085951408595Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal waterAseel Zaid0Yakubu Abdullahi Jarma1Islam Rashad Ahmed Senan2Aslı Karaoğlu3Aslı Karaoğlu4Aydın Cihanoğlu5Aydın Cihanoğlu6Alper Baba7Nalan Kabay8Department of Chemical Engineering, Ege University, Izmir, TürkiyeDepartment of Chemical Engineering, Ege University, Izmir, TürkiyeDepartment of Chemical Engineering, Ege University, Izmir, TürkiyeDepartment of Chemical Engineering, Ege University, Izmir, TürkiyeDepartment of Environmental Sciences, Graduate School of Natural and Applied Sciences, Ege University, Izmir, TürkiyeDepartment of Chemical Engineering, Ege University, Izmir, TürkiyeDepartment of Refinery and Petrochemical Technology, Aliağa Vocational School, Ege University, Izmir, TürkiyeDepartment of International Water Resources, Izmir Institute of Technology, Urla, TürkiyeDepartment of Chemical Engineering, Ege University, Izmir, TürkiyeIn this study, high mineral scaling propensity geothermal water was treated using a FilmTech BW30-2540 reverse osmosis (RO) membrane, integrated into a mini-pilot scale membrane test unit installed at a geothermal heating center. The study was conducted in eight cycles by monitoring membrane fouling via membrane flux decline. Firstly, the geothermal water coming from the source at approximately 80°C was taken into holding tanks and allowed to reach approximately room temperature (25°C). Then, the geothermal water that reached this temperature was used in the system. The fouling degree was compared to the initial permeability of the virgin membrane. After each treatment cycle, the membrane’s permeability was evaluated both before and after acid cleaning. Permeability testing was conducted using RO permeate as the feed, under pressures ranging from 8 to 30 bar, with 2-bar increments. The geothermal water treatment was performed at a constant pressure of 15 bar, with a water recovery maintained at approximately 50%. Prior to each permeability test, the membrane underwent a 45-min wash with citric acid, followed by a rinse with RO permeate. During the first five cycles, citric acid was used at a concentration of 1000 mg/L, achieving a flux recovery of 86.6% by the fifth cycle. In the subsequent three cycles, the citric acid concentration was increased to 4000 mg/L, resulting in a flux recovery of 63.4% by the eighth cycle. The study concluded that scale formation on the membrane surface intensified as the number of cycles increased.https://www.frontiersin.org/articles/10.3389/frmst.2024.1408595/fullgeothermal watermembrane foulingreverse osmosis (RO) membranescalingchemical cleaning
spellingShingle Aseel Zaid
Yakubu Abdullahi Jarma
Islam Rashad Ahmed Senan
Aslı Karaoğlu
Aslı Karaoğlu
Aydın Cihanoğlu
Aydın Cihanoğlu
Alper Baba
Nalan Kabay
Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
Frontiers in Membrane Science and Technology
geothermal water
membrane fouling
reverse osmosis (RO) membrane
scaling
chemical cleaning
title Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
title_full Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
title_fullStr Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
title_full_unstemmed Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
title_short Evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
title_sort evaluation of fouling and chemical cleaning of reverse osmosis membrane after treatment of geothermal water
topic geothermal water
membrane fouling
reverse osmosis (RO) membrane
scaling
chemical cleaning
url https://www.frontiersin.org/articles/10.3389/frmst.2024.1408595/full
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