Helical dislocation-driven plasticity and flexible high-performance thermoelectric generator in α-Mg3Bi2 single crystals
Abstract Inorganic plastic semiconductors play a crucial role in the realm of flexible electronics. In this study, we present a cost-effective plastic thermoelectric semimetal magnesium bismuthide (α-Mg3Bi2), exhibiting remarkable thermoelectric performance. Bulk single-crystalline α-Mg3Bi2 exhibits...
Saved in:
| Main Authors: | , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-01-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-024-55689-7 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | Abstract Inorganic plastic semiconductors play a crucial role in the realm of flexible electronics. In this study, we present a cost-effective plastic thermoelectric semimetal magnesium bismuthide (α-Mg3Bi2), exhibiting remarkable thermoelectric performance. Bulk single-crystalline α-Mg3Bi2 exhibits considerable plastic deformation at room temperature, allowing for the fabrication of intricate shapes such as the letters “SUSTECH” and a flexible chain. Transmission electron microscopy, time-of-flight neutron diffraction, and chemical bonding theoretic analyses elucidate that the plasticity of α-Mg3Bi2 stems from the helical dislocation-driven interlayer slip, small-sized Mg atoms induced weak interlayer Mg-Bi bonds, and low modulus of intralayer Mg2Bi2 2- networks. Moreover, we achieve a power factor value of up to 26.2 µW cm-1 K-2 along the c-axis at room temperature in an n-type α-Mg3Bi2 crystal. Our out-of-plane flexible thermoelectric generator exhibit a normalized power density of 8.1 μW cm-2 K-2 with a temperature difference of 7.3 K. This high-performance plastic thermoelectric semimetal promises to advance the field of flexible and deformable electronics. |
|---|---|
| ISSN: | 2041-1723 |