High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection

Abstract Flexible gas sensors are gaining interest for real‐time volatile gas monitoring. A natural rubber (NR)/MXene nanocomposite sensor is developed. Among the six selected target volatile gases, the composite sensor exhibited a strong response value (82% toward 100 ppm NH3) with the fastest resp...

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Main Authors: Na Kong, Ting Ren, Hui Yang, Mia Angela N. Judicpa, Ken Aldren S. Usman, Xu Zhao, Yanqiu Shao, Joselito M. Razal, Jinlong Tao, Jizhen Zhang
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:Advanced Materials Interfaces
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Online Access:https://doi.org/10.1002/admi.202400565
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author Na Kong
Ting Ren
Hui Yang
Mia Angela N. Judicpa
Ken Aldren S. Usman
Xu Zhao
Yanqiu Shao
Joselito M. Razal
Jinlong Tao
Jizhen Zhang
author_facet Na Kong
Ting Ren
Hui Yang
Mia Angela N. Judicpa
Ken Aldren S. Usman
Xu Zhao
Yanqiu Shao
Joselito M. Razal
Jinlong Tao
Jizhen Zhang
author_sort Na Kong
collection DOAJ
description Abstract Flexible gas sensors are gaining interest for real‐time volatile gas monitoring. A natural rubber (NR)/MXene nanocomposite sensor is developed. Among the six selected target volatile gases, the composite sensor exhibited a strong response value (82% toward 100 ppm NH3) with the fastest response/recovery time (12.3 s/15.5 s) to NH3. The sensitivity showed a clear dependence of gases, suggesting a good selectivity to varying gases. Ti3C2Tx MXene gas sensors exhibited a very low limit of detection of 50–100 ppb for volatile organic compounds (VOCs) at room temperature. In addition, the NR/MXene sensor allows detection of the mixture of ammonia (NH3), dimethyl sulfoxide (DMSO), and acetone (C3H6O) and it shows good response depending on the total concentration of VOC gases. Furthermore, the flexible nanocomposite sensor exhibits stable sensing performance at different bending states (0‐120°) and shows 20‐day atmospheric stability. This sensor's ability extends to alcohol breath analysis, useful for drunk driving detection. This work paves the way to the possibility of using robust MXene‐based toward practical realization of electronic devices.
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institution Kabale University
issn 2196-7350
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publishDate 2025-01-01
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series Advanced Materials Interfaces
spelling doaj-art-c9bd31543b8540e6896e0aa5a9124f802025-01-03T08:39:29ZengWiley-VCHAdvanced Materials Interfaces2196-73502025-01-01121n/an/a10.1002/admi.202400565High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC DetectionNa Kong0Ting Ren1Hui Yang2Mia Angela N. Judicpa3Ken Aldren S. Usman4Xu Zhao5Yanqiu Shao6Joselito M. Razal7Jinlong Tao8Jizhen Zhang9Hainan Provincial Key Laboratory of Natural Rubber Processing Agricultural Products Processing Research Institute Chinese Academy of Tropical Agricultural Sciences Zhanjiang 524001 ChinaHainan Provincial Key Laboratory of Natural Rubber Processing Agricultural Products Processing Research Institute Chinese Academy of Tropical Agricultural Sciences Zhanjiang 524001 ChinaHainan Provincial Key Laboratory of Natural Rubber Processing Agricultural Products Processing Research Institute Chinese Academy of Tropical Agricultural Sciences Zhanjiang 524001 ChinaInstitute for Frontier Materials Deakin University Geelong Victoria 3216 AustraliaInstitute for Frontier Materials Deakin University Geelong Victoria 3216 AustraliaHainan Provincial Key Laboratory of Natural Rubber Processing Agricultural Products Processing Research Institute Chinese Academy of Tropical Agricultural Sciences Zhanjiang 524001 ChinaCollege of Chemistry and Chemical Engineering Mu Danjiang Normal University Mudanjiang 157011 ChinaInstitute for Frontier Materials Deakin University Geelong Victoria 3216 AustraliaHainan Provincial Key Laboratory of Natural Rubber Processing Agricultural Products Processing Research Institute Chinese Academy of Tropical Agricultural Sciences Zhanjiang 524001 ChinaHainan Provincial Key Laboratory of Natural Rubber Processing Agricultural Products Processing Research Institute Chinese Academy of Tropical Agricultural Sciences Zhanjiang 524001 ChinaAbstract Flexible gas sensors are gaining interest for real‐time volatile gas monitoring. A natural rubber (NR)/MXene nanocomposite sensor is developed. Among the six selected target volatile gases, the composite sensor exhibited a strong response value (82% toward 100 ppm NH3) with the fastest response/recovery time (12.3 s/15.5 s) to NH3. The sensitivity showed a clear dependence of gases, suggesting a good selectivity to varying gases. Ti3C2Tx MXene gas sensors exhibited a very low limit of detection of 50–100 ppb for volatile organic compounds (VOCs) at room temperature. In addition, the NR/MXene sensor allows detection of the mixture of ammonia (NH3), dimethyl sulfoxide (DMSO), and acetone (C3H6O) and it shows good response depending on the total concentration of VOC gases. Furthermore, the flexible nanocomposite sensor exhibits stable sensing performance at different bending states (0‐120°) and shows 20‐day atmospheric stability. This sensor's ability extends to alcohol breath analysis, useful for drunk driving detection. This work paves the way to the possibility of using robust MXene‐based toward practical realization of electronic devices.https://doi.org/10.1002/admi.202400565flexible sensorgas sensorMXenenatural rubberVOC detection
spellingShingle Na Kong
Ting Ren
Hui Yang
Mia Angela N. Judicpa
Ken Aldren S. Usman
Xu Zhao
Yanqiu Shao
Joselito M. Razal
Jinlong Tao
Jizhen Zhang
High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection
Advanced Materials Interfaces
flexible sensor
gas sensor
MXene
natural rubber
VOC detection
title High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection
title_full High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection
title_fullStr High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection
title_full_unstemmed High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection
title_short High‐Performance Flexible Gas Sensor Using Natural Rubber/MXene Composite for Selective and Stable VOC Detection
title_sort high performance flexible gas sensor using natural rubber mxene composite for selective and stable voc detection
topic flexible sensor
gas sensor
MXene
natural rubber
VOC detection
url https://doi.org/10.1002/admi.202400565
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