Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells

Abstract The application of upconversion nanoparticles (UCNPs) for cell and tissue analysis requires a comprehensive understanding of their interactions with biological entities to prevent toxicity or harmful effects. Whereas most studies focus on cancer cells, this work addresses non-cancerous cell...

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Main Authors: Susanne Märkl, Frédéric Przybilla, Reinhard Rachel, Thomas Hirsch, Max Keller, Ralph Witzgall, Yves Mély, Joachim Wegener
Format: Article
Language:English
Published: Nature Portfolio 2024-12-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-024-83406-3
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author Susanne Märkl
Frédéric Przybilla
Reinhard Rachel
Thomas Hirsch
Max Keller
Ralph Witzgall
Yves Mély
Joachim Wegener
author_facet Susanne Märkl
Frédéric Przybilla
Reinhard Rachel
Thomas Hirsch
Max Keller
Ralph Witzgall
Yves Mély
Joachim Wegener
author_sort Susanne Märkl
collection DOAJ
description Abstract The application of upconversion nanoparticles (UCNPs) for cell and tissue analysis requires a comprehensive understanding of their interactions with biological entities to prevent toxicity or harmful effects. Whereas most studies focus on cancer cells, this work addresses non-cancerous cells with their regular in vitro physiology. Since it is generally accepted that surface chemistry largely determines biocompatibility in general and uptake of nanomaterials in particular, two bilayer surface coatings with different surface shielding properties have been studied: (i) a phospholipid bilayer membrane (PLM) and (ii) an amphiphilic polymer (AP). Both surface modifications are applied to (12–33) nm core-shell UCNPs NaYF4(Yb, Er)@NaYF4, ensuring colloidal stability in biological media. The impact of UCNPs@AP and UCNPs@PLM on non-cancerous epithelial-like kidney cells in vitro was found to differ significantly. UCNPs@PLM did not exhibit any measurable effect on cell physiology, even with prolonged exposure. In contrast, UCNPs@AP caused changes in cell morphology and induced cell-death after approximately 30 h. These variations in toxicity are attributed to the distinct chemical stability of these particles, which likely influences their intracellular disintegration.
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publishDate 2024-12-01
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spelling doaj-art-c97b62bee6c4420ea57d26cf74e4e7fb2024-12-29T12:21:00ZengNature PortfolioScientific Reports2045-23222024-12-0114111110.1038/s41598-024-83406-3Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cellsSusanne Märkl0Frédéric Przybilla1Reinhard Rachel2Thomas Hirsch3Max Keller4Ralph Witzgall5Yves Mély6Joachim Wegener7Institute for Analytical Chemistry, Chemo- and Biosensors, University of RegensburgLaboratory of Bioimaging and Pathologies, UMR 7021 CNRS, University of StrasbourgCentre for EM, University of RegensburgInstitute for Analytical Chemistry, Chemo- and Biosensors, University of RegensburgInstitute for Pharmacy, University of RegensburgInstitute for Anatomy, University of RegensburgLaboratory of Bioimaging and Pathologies, UMR 7021 CNRS, University of StrasbourgInstitute for Analytical Chemistry, Chemo- and Biosensors, University of RegensburgAbstract The application of upconversion nanoparticles (UCNPs) for cell and tissue analysis requires a comprehensive understanding of their interactions with biological entities to prevent toxicity or harmful effects. Whereas most studies focus on cancer cells, this work addresses non-cancerous cells with their regular in vitro physiology. Since it is generally accepted that surface chemistry largely determines biocompatibility in general and uptake of nanomaterials in particular, two bilayer surface coatings with different surface shielding properties have been studied: (i) a phospholipid bilayer membrane (PLM) and (ii) an amphiphilic polymer (AP). Both surface modifications are applied to (12–33) nm core-shell UCNPs NaYF4(Yb, Er)@NaYF4, ensuring colloidal stability in biological media. The impact of UCNPs@AP and UCNPs@PLM on non-cancerous epithelial-like kidney cells in vitro was found to differ significantly. UCNPs@PLM did not exhibit any measurable effect on cell physiology, even with prolonged exposure. In contrast, UCNPs@AP caused changes in cell morphology and induced cell-death after approximately 30 h. These variations in toxicity are attributed to the distinct chemical stability of these particles, which likely influences their intracellular disintegration.https://doi.org/10.1038/s41598-024-83406-3
spellingShingle Susanne Märkl
Frédéric Przybilla
Reinhard Rachel
Thomas Hirsch
Max Keller
Ralph Witzgall
Yves Mély
Joachim Wegener
Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells
Scientific Reports
title Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells
title_full Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells
title_fullStr Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells
title_full_unstemmed Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells
title_short Impact of surface chemistry of upconversion nanoparticles on time-dependent cytotoxicity in non-cancerous epithelial cells
title_sort impact of surface chemistry of upconversion nanoparticles on time dependent cytotoxicity in non cancerous epithelial cells
url https://doi.org/10.1038/s41598-024-83406-3
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