Adsorption analysis of organic and chemical sorbents for oil spill management on land

This study aims to evaluate the effectiveness of chemical and biodegradable agricultural waste sorbents in remediating oil spill-contaminated well sites in the upper Assam Basin of India. The study involved laboratory analyses to analyze the physical characteristics of oil-spill fluids and evaluate...

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Main Authors: Sanjukta Baruah, Dhrubajyoti Neog
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025012423
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author Sanjukta Baruah
Dhrubajyoti Neog
author_facet Sanjukta Baruah
Dhrubajyoti Neog
author_sort Sanjukta Baruah
collection DOAJ
description This study aims to evaluate the effectiveness of chemical and biodegradable agricultural waste sorbents in remediating oil spill-contaminated well sites in the upper Assam Basin of India. The study involved laboratory analyses to analyze the physical characteristics of oil-spill fluids and evaluate the impact of spillage on soil. Soil samples were tested for pH, organic carbon, potash, sulfur, phosphate, and total nitrogen. Soil characteristics before and after the spills were compared. Of the five soil samples examined, three were treated with two chemical sorbents (sodium lauryl sulfate and sodium dodecylbenzene sulfonate) and one biosorbent was made from agricultural waste (rice husk). Rice husks were chosen because of their abundant availability in the area. The adsorption performance of the chemical sorbents was evaluated using wettability analysis, and the sorbent absorption behavior was investigated using UV–visible spectrophotometry. The findings of this study emphasize the use of organic sorbents to remediate hydrocarbon-contaminated sites, presenting them as cost-effective and environmentally safe alternatives to chemical sorbents. Based on the soil testing results of pre- and post-sorbent treatments with sodium dodecylbenzene sulfonate (SDBS), it was observed that SDBS improved the pH to 9.69 from 6.68; organic matter to 5.33 from 0.74; organic carbon to 3.09 % from 0.43 %; available potash (K₂O ppm) to 83 ppm from 20 ppm; sulfur content to 68 ppm from 50 ppm; available phosphate (P₂O₅) to 27 ppm from 13 ppm; and % nitrogen to 0.262. These values infer higher performance of SDBS sorbent than sodium lauryl sulfate sorbent. In addition, the sorption capacity of organic sorbent (rice husk) increased to 1.255 g/g.
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spelling doaj-art-c94e1922d9314d01b7a3028edf111c9a2025-08-20T03:53:13ZengElsevierResults in Engineering2590-12302025-06-012610516710.1016/j.rineng.2025.105167Adsorption analysis of organic and chemical sorbents for oil spill management on landSanjukta Baruah0Dhrubajyoti Neog1Oil India Limited, Duliajan, IndiaDepartment of Petroleum Technology, Dibrugarh University, India; Corresponding author.This study aims to evaluate the effectiveness of chemical and biodegradable agricultural waste sorbents in remediating oil spill-contaminated well sites in the upper Assam Basin of India. The study involved laboratory analyses to analyze the physical characteristics of oil-spill fluids and evaluate the impact of spillage on soil. Soil samples were tested for pH, organic carbon, potash, sulfur, phosphate, and total nitrogen. Soil characteristics before and after the spills were compared. Of the five soil samples examined, three were treated with two chemical sorbents (sodium lauryl sulfate and sodium dodecylbenzene sulfonate) and one biosorbent was made from agricultural waste (rice husk). Rice husks were chosen because of their abundant availability in the area. The adsorption performance of the chemical sorbents was evaluated using wettability analysis, and the sorbent absorption behavior was investigated using UV–visible spectrophotometry. The findings of this study emphasize the use of organic sorbents to remediate hydrocarbon-contaminated sites, presenting them as cost-effective and environmentally safe alternatives to chemical sorbents. Based on the soil testing results of pre- and post-sorbent treatments with sodium dodecylbenzene sulfonate (SDBS), it was observed that SDBS improved the pH to 9.69 from 6.68; organic matter to 5.33 from 0.74; organic carbon to 3.09 % from 0.43 %; available potash (K₂O ppm) to 83 ppm from 20 ppm; sulfur content to 68 ppm from 50 ppm; available phosphate (P₂O₅) to 27 ppm from 13 ppm; and % nitrogen to 0.262. These values infer higher performance of SDBS sorbent than sodium lauryl sulfate sorbent. In addition, the sorption capacity of organic sorbent (rice husk) increased to 1.255 g/g.http://www.sciencedirect.com/science/article/pii/S2590123025012423Oil spillSorbentsWellfluidSoil sampleOil well siteAdsorption capacity
spellingShingle Sanjukta Baruah
Dhrubajyoti Neog
Adsorption analysis of organic and chemical sorbents for oil spill management on land
Results in Engineering
Oil spill
Sorbents
Wellfluid
Soil sample
Oil well site
Adsorption capacity
title Adsorption analysis of organic and chemical sorbents for oil spill management on land
title_full Adsorption analysis of organic and chemical sorbents for oil spill management on land
title_fullStr Adsorption analysis of organic and chemical sorbents for oil spill management on land
title_full_unstemmed Adsorption analysis of organic and chemical sorbents for oil spill management on land
title_short Adsorption analysis of organic and chemical sorbents for oil spill management on land
title_sort adsorption analysis of organic and chemical sorbents for oil spill management on land
topic Oil spill
Sorbents
Wellfluid
Soil sample
Oil well site
Adsorption capacity
url http://www.sciencedirect.com/science/article/pii/S2590123025012423
work_keys_str_mv AT sanjuktabaruah adsorptionanalysisoforganicandchemicalsorbentsforoilspillmanagementonland
AT dhrubajyotineog adsorptionanalysisoforganicandchemicalsorbentsforoilspillmanagementonland