Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer

Purpose: Oil Palm Empty Fruit Bunches (OPEFB) solid waste has potential as a feedstock to be transformed into nanocellulose and activated carbon. In this study, we observed the effect of various compositions of activated carbon, alginate, and nanocellulose on the production of micronutrient slow-re...

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Main Authors: Zainuddin Muchtar, Siti Rahmah, Moondra Zubir, Putri Faradilla, Rini Selly, Ahmad Shafwan Pulungan, Lisna Efiyanti, Riska Cahyati, Atikah Nur Syahirah
Format: Article
Language:English
Published: OICC Press 2025-01-01
Series:International Journal of Recycling of Organic Waste in Agriculture
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Online Access:https://oiccpress.com/ijrowa/article/view/8457
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author Zainuddin Muchtar
Siti Rahmah
Moondra Zubir
Putri Faradilla
Rini Selly
Ahmad Shafwan Pulungan
Lisna Efiyanti
Riska Cahyati
Atikah Nur Syahirah
author_facet Zainuddin Muchtar
Siti Rahmah
Moondra Zubir
Putri Faradilla
Rini Selly
Ahmad Shafwan Pulungan
Lisna Efiyanti
Riska Cahyati
Atikah Nur Syahirah
author_sort Zainuddin Muchtar
collection DOAJ
description Purpose: Oil Palm Empty Fruit Bunches (OPEFB) solid waste has potential as a feedstock to be transformed into nanocellulose and activated carbon. In this study, we observed the effect of various compositions of activated carbon, alginate, and nanocellulose on the production of micronutrient slow-release fertilizer composites. Method: The composite of activated carbon/alginate/nanocellulose (C/Alg/NC) with various compositions of 1:1:1; 3:1:1; 1:3:1 and 1:1:3 was synthesized and characterized by using FTIR, XRD, and SEM-EDX analysis. Crosslinked effects by Cu and Fe were observed, and composite C/Alg/NC showed slower release of Cu ions, which indicates a good strategy to produce micronutrient slow-release fertilizer. Results: The best composite as a slow-release fertilizer for Cu metal is a 3:1:1 ratio. Over two days, it released 0.05 mg/g, and on the third day, it released an increase up to 0.27 mg/g after five days. Meanwhile, the Fe crosslinker composite with the same composition ratio (1:1:1) performed best as a slow-release fertilizer because Fe released slowly at only around 0.05 mg/g for up to three days. Then, for the next three days, until the 6th day, Fe was released slightly more, up to 0.3 mg/g, and then remained constant until the 9th day. Conclusion: The synthesis of composites from a combination of carbon, alginate, and nanocellulose has become a good strategy for producing slow-release fertilizer. It has also become a solution for utilizing OPEFB solid waste, while this slow-release fertilizer can be used as a source of plant nutrition in oil palm plantations. Research Highlights • Activated carbon and nanocellulose synthesis from sild waste Oil Palm Empty Fruit Bunches (OPEFB) • Composite synthesis with various composition of alginate-activated carbon-nanocellulose • Crosslinker effect of Cu and Fe metal on composite synthesis • Observed release of Cu and Fe as micronutrient slow-release fertilizer
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series International Journal of Recycling of Organic Waste in Agriculture
spelling doaj-art-c760a5fd62064c6b98f908ea7b12a2bd2025-01-14T11:18:36ZengOICC PressInternational Journal of Recycling of Organic Waste in Agriculture2195-32282251-77152025-01-0110.57647/ijrowa-n3ya-7856Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizerZainuddin Muchtar 0https://orcid.org/0000-0002-8805-5553Siti Rahmah1https://orcid.org/0000-0001-7950-0996Moondra Zubir2https://orcid.org/0000-0002-4619-757XPutri Faradilla3https://orcid.org/0009-0007-1349-8951Rini Selly4https://orcid.org/0000-0003-2087-0081Ahmad Shafwan Pulungan5https://orcid.org/0000-0002-4628-3515Lisna Efiyanti6https://orcid.org/0000-0002-9200-541XRiska Cahyati7https://orcid.org/0009-0005-2919-1634Atikah Nur Syahirah8https://orcid.org/0009-0002-5884-2414Chemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Chemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Chemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Chemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Chemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Biology Department, Faculty of Mathematics and Natural Science, State University of Medan, Medan, North Sumatera, IndonesiaResearch Center for Biomass and Bioproduct, Nasional research and innovation agency, IndonesiaChemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Chemistry Department, Faculty of Mathematics and Natural Science, Universitas Negeri Medan, Medan, Indonesia Purpose: Oil Palm Empty Fruit Bunches (OPEFB) solid waste has potential as a feedstock to be transformed into nanocellulose and activated carbon. In this study, we observed the effect of various compositions of activated carbon, alginate, and nanocellulose on the production of micronutrient slow-release fertilizer composites. Method: The composite of activated carbon/alginate/nanocellulose (C/Alg/NC) with various compositions of 1:1:1; 3:1:1; 1:3:1 and 1:1:3 was synthesized and characterized by using FTIR, XRD, and SEM-EDX analysis. Crosslinked effects by Cu and Fe were observed, and composite C/Alg/NC showed slower release of Cu ions, which indicates a good strategy to produce micronutrient slow-release fertilizer. Results: The best composite as a slow-release fertilizer for Cu metal is a 3:1:1 ratio. Over two days, it released 0.05 mg/g, and on the third day, it released an increase up to 0.27 mg/g after five days. Meanwhile, the Fe crosslinker composite with the same composition ratio (1:1:1) performed best as a slow-release fertilizer because Fe released slowly at only around 0.05 mg/g for up to three days. Then, for the next three days, until the 6th day, Fe was released slightly more, up to 0.3 mg/g, and then remained constant until the 9th day. Conclusion: The synthesis of composites from a combination of carbon, alginate, and nanocellulose has become a good strategy for producing slow-release fertilizer. It has also become a solution for utilizing OPEFB solid waste, while this slow-release fertilizer can be used as a source of plant nutrition in oil palm plantations. Research Highlights • Activated carbon and nanocellulose synthesis from sild waste Oil Palm Empty Fruit Bunches (OPEFB) • Composite synthesis with various composition of alginate-activated carbon-nanocellulose • Crosslinker effect of Cu and Fe metal on composite synthesis • Observed release of Cu and Fe as micronutrient slow-release fertilizer https://oiccpress.com/ijrowa/article/view/8457CompostCross Linker SynthesisOil Palm Empty Fruit BunchesPlant Nutrition
spellingShingle Zainuddin Muchtar
Siti Rahmah
Moondra Zubir
Putri Faradilla
Rini Selly
Ahmad Shafwan Pulungan
Lisna Efiyanti
Riska Cahyati
Atikah Nur Syahirah
Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer
International Journal of Recycling of Organic Waste in Agriculture
Compost
Cross Linker Synthesis
Oil Palm Empty Fruit Bunches
Plant Nutrition
title Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer
title_full Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer
title_fullStr Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer
title_full_unstemmed Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer
title_short Crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow-release fertilizer
title_sort crosslinker effect on composite synthesis of alginate with activated carbon and nanocellulose as micronutrient slow release fertilizer
topic Compost
Cross Linker Synthesis
Oil Palm Empty Fruit Bunches
Plant Nutrition
url https://oiccpress.com/ijrowa/article/view/8457
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