Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative
The utilization of catalysts in organic reactions represents a widely utilized principle within the concept of green chemistry. This study focuses on utilizing hydroxyapatite from green mussel shell waste combined with CoFe2O4 as a heterogeneous catalyst for synthesizing 2-amino-4H-chromene derivati...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2024-12-01
|
| Series: | Case Studies in Chemical and Environmental Engineering |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666016424002457 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1846145982816845824 |
|---|---|
| author | Agus Rimus Liandi Anggi Amirudin Al-wahid Yusraini Dian Inayati Siregar Tio Putra Wendari Antonius Herry Cahyana Andon Insani |
| author_facet | Agus Rimus Liandi Anggi Amirudin Al-wahid Yusraini Dian Inayati Siregar Tio Putra Wendari Antonius Herry Cahyana Andon Insani |
| author_sort | Agus Rimus Liandi |
| collection | DOAJ |
| description | The utilization of catalysts in organic reactions represents a widely utilized principle within the concept of green chemistry. This study focuses on utilizing hydroxyapatite from green mussel shell waste combined with CoFe2O4 as a heterogeneous catalyst for synthesizing 2-amino-4H-chromene derivative. The green mussel shells were calcined to produce CaO, which was then utilized as a precursor in the synthesis of hydroxyapatite, and then combined with cobalt ferrite through the coprecipitation method. Diffractogram analysis confirmed successful formation of hydroxyapatite, CoFe2O4, and their composite, validated against JCPDS data. Morphological analysis revealed irregular shapes, while magnetic property analysis indicated a slight decrease in the hydroxyapatite-CoFe2O4 composite compared to pristine CoFe2O4. Catalytic activity assessment demonstrated high yields (up to 88 %) under optimized conditions: catalyst concentration of 7.5 % w/w, reaction time of 15 minutes, in ethanol solvent, and using 300 Watts microwave power. The reusability of hydroxyapatite-CoFe2O4 as a catalyst, supported by the XRD and FTIR analyses, demonstrates its structural and chemical stability after five catalytic cycles, showcasing its potential as an eco-friendly and efficient catalyst. |
| format | Article |
| id | doaj-art-c72514864dda4b06b60fc958fd88ad65 |
| institution | Kabale University |
| issn | 2666-0164 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Case Studies in Chemical and Environmental Engineering |
| spelling | doaj-art-c72514864dda4b06b60fc958fd88ad652024-12-02T05:05:49ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642024-12-0110100851Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivativeAgus Rimus Liandi0Anggi Amirudin Al-wahid1Yusraini Dian Inayati Siregar2Tio Putra Wendari3Antonius Herry Cahyana4Andon Insani5Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Syarif Hidayatullah Jakarta, Tangerang Selatan, 15412, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Syarif Hidayatullah Jakarta, Tangerang Selatan, 15412, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Syarif Hidayatullah Jakarta, Tangerang Selatan, 15412, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Andalas, Kampus Limau Manis, Padang, 25163, Indonesia; Corresponding author.Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok, 16424, IndonesiaNuclear Energy Research Organization, National Research and Innovation Agency (BRIN), Tangerang Selatan, 15314, IndonesiaThe utilization of catalysts in organic reactions represents a widely utilized principle within the concept of green chemistry. This study focuses on utilizing hydroxyapatite from green mussel shell waste combined with CoFe2O4 as a heterogeneous catalyst for synthesizing 2-amino-4H-chromene derivative. The green mussel shells were calcined to produce CaO, which was then utilized as a precursor in the synthesis of hydroxyapatite, and then combined with cobalt ferrite through the coprecipitation method. Diffractogram analysis confirmed successful formation of hydroxyapatite, CoFe2O4, and their composite, validated against JCPDS data. Morphological analysis revealed irregular shapes, while magnetic property analysis indicated a slight decrease in the hydroxyapatite-CoFe2O4 composite compared to pristine CoFe2O4. Catalytic activity assessment demonstrated high yields (up to 88 %) under optimized conditions: catalyst concentration of 7.5 % w/w, reaction time of 15 minutes, in ethanol solvent, and using 300 Watts microwave power. The reusability of hydroxyapatite-CoFe2O4 as a catalyst, supported by the XRD and FTIR analyses, demonstrates its structural and chemical stability after five catalytic cycles, showcasing its potential as an eco-friendly and efficient catalyst.http://www.sciencedirect.com/science/article/pii/S2666016424002457Green synthesisCobalt ferriteHydroxyapatiteGreen mussel shell2-Amino-4H-chromene |
| spellingShingle | Agus Rimus Liandi Anggi Amirudin Al-wahid Yusraini Dian Inayati Siregar Tio Putra Wendari Antonius Herry Cahyana Andon Insani Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative Case Studies in Chemical and Environmental Engineering Green synthesis Cobalt ferrite Hydroxyapatite Green mussel shell 2-Amino-4H-chromene |
| title | Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative |
| title_full | Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative |
| title_fullStr | Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative |
| title_full_unstemmed | Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative |
| title_short | Green mussel shell-derived hydroxyapatite-CoFe2O4 catalyst: Microwave-assisted synthesis of 2-amino-4H-chromene derivative |
| title_sort | green mussel shell derived hydroxyapatite cofe2o4 catalyst microwave assisted synthesis of 2 amino 4h chromene derivative |
| topic | Green synthesis Cobalt ferrite Hydroxyapatite Green mussel shell 2-Amino-4H-chromene |
| url | http://www.sciencedirect.com/science/article/pii/S2666016424002457 |
| work_keys_str_mv | AT agusrimusliandi greenmusselshellderivedhydroxyapatitecofe2o4catalystmicrowaveassistedsynthesisof2amino4hchromenederivative AT anggiamirudinalwahid greenmusselshellderivedhydroxyapatitecofe2o4catalystmicrowaveassistedsynthesisof2amino4hchromenederivative AT yusrainidianinayatisiregar greenmusselshellderivedhydroxyapatitecofe2o4catalystmicrowaveassistedsynthesisof2amino4hchromenederivative AT tioputrawendari greenmusselshellderivedhydroxyapatitecofe2o4catalystmicrowaveassistedsynthesisof2amino4hchromenederivative AT antoniusherrycahyana greenmusselshellderivedhydroxyapatitecofe2o4catalystmicrowaveassistedsynthesisof2amino4hchromenederivative AT andoninsani greenmusselshellderivedhydroxyapatitecofe2o4catalystmicrowaveassistedsynthesisof2amino4hchromenederivative |