A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing

Catalyst deactivation and regeneration are critical aspects of heavy oil hydroprocessing. This review provides a comprehensive overview of the factors contributing to catalyst deactivation, including coke formation, metal and other heteroelement poisoning, and active metal sintering. We delve into t...

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Main Authors: Phuong T.H. Pham, Cham Q. Pham, Thi-Tam Dam, Quang-Anh Nguyen, Tung M. Nguyen
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Fuel Processing Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S0378382024001401
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author Phuong T.H. Pham
Cham Q. Pham
Thi-Tam Dam
Quang-Anh Nguyen
Tung M. Nguyen
author_facet Phuong T.H. Pham
Cham Q. Pham
Thi-Tam Dam
Quang-Anh Nguyen
Tung M. Nguyen
author_sort Phuong T.H. Pham
collection DOAJ
description Catalyst deactivation and regeneration are critical aspects of heavy oil hydroprocessing. This review provides a comprehensive overview of the factors contributing to catalyst deactivation, including coke formation, metal and other heteroelement poisoning, and active metal sintering. We delve into the mechanisms underlying these deactivation processes and discuss their impact on catalyst performance and reactor operations. Furthermore, the review explores various catalyst regeneration techniques, such as combustion and gasification techniques. We evaluate the effectiveness of these methods in removing coke and restoring catalyst activity. Additionally, we discuss strategies for mitigating coke formation, including the development of more coke-resistant catalysts and the addition of solvents and surfactants. Refineries can optimize their operations, improve product yields, and minimize environmental impact by understanding the causes of catalyst deactivation and the effectiveness of different regeneration techniques.
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publishDate 2025-03-01
publisher Elsevier
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series Fuel Processing Technology
spelling doaj-art-c6db84c727dc47b4a69f32b734ff13b92025-01-15T04:11:32ZengElsevierFuel Processing Technology0378-38202025-03-01267108170A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessingPhuong T.H. Pham0Cham Q. Pham1Thi-Tam Dam2Quang-Anh Nguyen3Tung M. Nguyen4Faculty of Chemical Engineering, Industrial University of Ho Chi Minh City (IUH), Ho Chi Minh City, Viet NamLow-Carbon Emission Control R&D Department, Korea Institute of Industrial Technology (KITECH), Cheonan, Republic of Korea; Green Process and Energy System Engineering, University of Science and Technology (UST), Daejeon, Republic of KoreaDepartment of Radiochemistry, Hanoi Irradiation Center, Vietnam Atomic Energy Institute, Hanoi, Viet NamDepartment of Radiochemistry, Hanoi Irradiation Center, Vietnam Atomic Energy Institute, Hanoi, Viet NamChemical Engineering, Competence Centre for Catalysis, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; Corresponding author.Catalyst deactivation and regeneration are critical aspects of heavy oil hydroprocessing. This review provides a comprehensive overview of the factors contributing to catalyst deactivation, including coke formation, metal and other heteroelement poisoning, and active metal sintering. We delve into the mechanisms underlying these deactivation processes and discuss their impact on catalyst performance and reactor operations. Furthermore, the review explores various catalyst regeneration techniques, such as combustion and gasification techniques. We evaluate the effectiveness of these methods in removing coke and restoring catalyst activity. Additionally, we discuss strategies for mitigating coke formation, including the development of more coke-resistant catalysts and the addition of solvents and surfactants. Refineries can optimize their operations, improve product yields, and minimize environmental impact by understanding the causes of catalyst deactivation and the effectiveness of different regeneration techniques.http://www.sciencedirect.com/science/article/pii/S0378382024001401Heavy oil upgradingCatalyst deactivationCoke formationMetal sinteringCatalyst regenerationCoke mitigation
spellingShingle Phuong T.H. Pham
Cham Q. Pham
Thi-Tam Dam
Quang-Anh Nguyen
Tung M. Nguyen
A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
Fuel Processing Technology
Heavy oil upgrading
Catalyst deactivation
Coke formation
Metal sintering
Catalyst regeneration
Coke mitigation
title A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
title_full A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
title_fullStr A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
title_full_unstemmed A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
title_short A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
title_sort comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing
topic Heavy oil upgrading
Catalyst deactivation
Coke formation
Metal sintering
Catalyst regeneration
Coke mitigation
url http://www.sciencedirect.com/science/article/pii/S0378382024001401
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