Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products
The development of technologies for processing oil residues is relevant and promising for Kazakhstan, since the main oil reserves of hydrocarbons in the country are in heavy oils. This paper describes the study of the influence of technological modes on the yield and hydrocarbon composition of produ...
Saved in:
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2022-07-01
|
| Series: | Chimica Techno Acta |
| Subjects: | |
| Online Access: | https://chimicatechnoacta.ru/article/view/5974 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1846109600914341888 |
|---|---|
| author | Tatyana V. Shakiyeva Larissa R. Sassykova Anastassiya A. Khamlenko Ulzhan N. Dzhatkambayeva Albina R. Sassykova Aigul A. Batyrbayeva Zhanar M. Zhaxibayeva Akmaral G. Ismailova Subramanian Sendilvelan |
| author_facet | Tatyana V. Shakiyeva Larissa R. Sassykova Anastassiya A. Khamlenko Ulzhan N. Dzhatkambayeva Albina R. Sassykova Aigul A. Batyrbayeva Zhanar M. Zhaxibayeva Akmaral G. Ismailova Subramanian Sendilvelan |
| author_sort | Tatyana V. Shakiyeva |
| collection | DOAJ |
| description | The development of technologies for processing oil residues is relevant and promising for Kazakhstan, since the main oil reserves of hydrocarbons in the country are in heavy oils. This paper describes the study of the influence of technological modes on the yield and hydrocarbon composition of products formed because of cracking of commercial fuel oil and fuel oil M-100 in the presence of air in the reactor. For catalysts preparation, natural Taizhuzgen zeolite and Narynkol clay were used. It was found that the introduction of air into the reaction zone, in which oxygen is the initiator of the cracking process, significantly increases the yield of the middle distillate fractions. In the presence of air, the yield of diene and cyclodiene hydrocarbons significantly increases compared to cracking in an inert atmosphere. According to the data of IR spectral analysis of M-100 grade oil fractions, in addition to normal alkanes, the final sample contains a significant amount of olefinic and aromatic hydrocarbons. On the optimal catalyst, owing to oxidative cracking of fuel oil, the following product compositions (in %) were established: Fuel oil M-100: gas – 0.8, gasoline – 1.1, light gas oil – 85.7, heavy residue – 11.9, loss – 0.5 and total – 100.0%; commodity Fuel oil (M-100): gas – 3.3, gasoline – 8.4, light gas oil – 84.3, heavy residue – 4.0, loss – 0 and total – 100.0%. |
| format | Article |
| id | doaj-art-c449fe61d5044e578fc474b24ea0f041 |
| institution | Kabale University |
| issn | 2411-1414 |
| language | English |
| publishDate | 2022-07-01 |
| publisher | Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj-art-c449fe61d5044e578fc474b24ea0f0412024-12-25T09:36:55ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142022-07-019310.15826/chimtech.2022.9.3.014491Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion productsTatyana V. Shakiyeva0Larissa R. Sassykova1Anastassiya A. Khamlenko2Ulzhan N. Dzhatkambayeva3Albina R. Sassykova4Aigul A. Batyrbayeva5Zhanar M. Zhaxibayeva6Akmaral G. Ismailova7Subramanian Sendilvelan8Al-Farabi Kazakh National UniversityAl-Farabi Kazakh National UniversityAl-Farabi Kazakh National UniversityAl-Farabi Kazakh National UniversityAlmaty College of Economics and LawAl-Farabi Kazakh National UniversityAbai Kazakh National Pedagogical UniversityAl-Farabi Kazakh National UniversityDepartment of Mechanical Engineering, Dr.Sc. M.G.R Educational and Research InstituteThe development of technologies for processing oil residues is relevant and promising for Kazakhstan, since the main oil reserves of hydrocarbons in the country are in heavy oils. This paper describes the study of the influence of technological modes on the yield and hydrocarbon composition of products formed because of cracking of commercial fuel oil and fuel oil M-100 in the presence of air in the reactor. For catalysts preparation, natural Taizhuzgen zeolite and Narynkol clay were used. It was found that the introduction of air into the reaction zone, in which oxygen is the initiator of the cracking process, significantly increases the yield of the middle distillate fractions. In the presence of air, the yield of diene and cyclodiene hydrocarbons significantly increases compared to cracking in an inert atmosphere. According to the data of IR spectral analysis of M-100 grade oil fractions, in addition to normal alkanes, the final sample contains a significant amount of olefinic and aromatic hydrocarbons. On the optimal catalyst, owing to oxidative cracking of fuel oil, the following product compositions (in %) were established: Fuel oil M-100: gas – 0.8, gasoline – 1.1, light gas oil – 85.7, heavy residue – 11.9, loss – 0.5 and total – 100.0%; commodity Fuel oil (M-100): gas – 3.3, gasoline – 8.4, light gas oil – 84.3, heavy residue – 4.0, loss – 0 and total – 100.0%.https://chimicatechnoacta.ru/article/view/5974catalytic crackingoxidative crackingnatural zeolitetaizhuzgen zeolitenarynkol clayamangeldy gppfuel oil m-100 |
| spellingShingle | Tatyana V. Shakiyeva Larissa R. Sassykova Anastassiya A. Khamlenko Ulzhan N. Dzhatkambayeva Albina R. Sassykova Aigul A. Batyrbayeva Zhanar M. Zhaxibayeva Akmaral G. Ismailova Subramanian Sendilvelan Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products Chimica Techno Acta catalytic cracking oxidative cracking natural zeolite taizhuzgen zeolite narynkol clay amangeldy gpp fuel oil m-100 |
| title | Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products |
| title_full | Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products |
| title_fullStr | Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products |
| title_full_unstemmed | Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products |
| title_short | Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products |
| title_sort | catalytic cracking of m 100 fuel oil relationships between origin process parameters and conversion products |
| topic | catalytic cracking oxidative cracking natural zeolite taizhuzgen zeolite narynkol clay amangeldy gpp fuel oil m-100 |
| url | https://chimicatechnoacta.ru/article/view/5974 |
| work_keys_str_mv | AT tatyanavshakiyeva catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT larissarsassykova catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT anastassiyaakhamlenko catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT ulzhanndzhatkambayeva catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT albinarsassykova catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT aigulabatyrbayeva catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT zhanarmzhaxibayeva catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT akmaralgismailova catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts AT subramaniansendilvelan catalyticcrackingofm100fueloilrelationshipsbetweenoriginprocessparametersandconversionproducts |