Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation

Supramolecular gel can be used to seal fractures and pores in the formation during oil and gas drilling and production. In this study, a supramolecular gel plugging agent based on hydrophobic association was prepared by free radical polymerization of acrylamide, octadecyl methacrylate, sodium dodecy...

Full description

Saved in:
Bibliographic Details
Main Authors: Yongquan Han, Zhixue Yu, Zijun Guan, Rui Ma, Yuzhou Hu
Format: Article
Language:English
Published: Frontiers Media S.A. 2024-11-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2024.1468766/full
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1846156482134933504
author Yongquan Han
Zhixue Yu
Zijun Guan
Rui Ma
Yuzhou Hu
author_facet Yongquan Han
Zhixue Yu
Zijun Guan
Rui Ma
Yuzhou Hu
author_sort Yongquan Han
collection DOAJ
description Supramolecular gel can be used to seal fractures and pores in the formation during oil and gas drilling and production. In this study, a supramolecular gel plugging agent based on hydrophobic association was prepared by free radical polymerization of acrylamide, octadecyl methacrylate, sodium dodecyl sulfate and other monomers by micellar copolymerization. The forming time, rheology, swelling, mechanical properties and plugging properties of supramolecular gels were studied. The experimental results show that the formation time of supramolecular gel plugging agent is controllable, and it has excellent viscoelastic recovery ability in a certain range of shear strain and scanning frequency. When the compression amount is close to 88.3%, the compressive stress reaches 3.82 MPa. Meanwhile, the swelling performance of supramolecular gel was good, and the equilibrium swelling degree reached 22.1% after 188 min swelling in 15% NaCl brine solution. In 1% NaCl solution, the equilibrium swelling degree of supramolecular gel reached 32.5%. In addition, supramolecular gel has strong formation bonding ability, good plugging performance, plugging rate is greater than 95%, can effectively reduce the leakage and improve the plugging effect of low permeability layer. It is of reference and guiding significance for the long-term plugging of heterogeneous and malignant leakage formations.
format Article
id doaj-art-c16e085df88d43c795345c9eb5c65489
institution Kabale University
issn 2296-2646
language English
publishDate 2024-11-01
publisher Frontiers Media S.A.
record_format Article
series Frontiers in Chemistry
spelling doaj-art-c16e085df88d43c795345c9eb5c654892024-11-26T04:25:50ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462024-11-011210.3389/fchem.2024.14687661468766Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formationYongquan Han0Zhixue Yu1Zijun Guan2Rui Ma3Yuzhou Hu4The Ninth Oil Extraction Plant of Changqing Oilfield Company, Xi’an, ChinaThe Ninth Oil Extraction Plant of Changqing Oilfield Company, Xi’an, ChinaPetrochina Liaohe Oil Production Technology Research Institute, Liaoning, ChinaThe Ninth Oil Extraction Plant of Changqing Oilfield Company, Xi’an, ChinaThe Ninth Oil Extraction Plant of Changqing Oilfield Company, Xi’an, ChinaSupramolecular gel can be used to seal fractures and pores in the formation during oil and gas drilling and production. In this study, a supramolecular gel plugging agent based on hydrophobic association was prepared by free radical polymerization of acrylamide, octadecyl methacrylate, sodium dodecyl sulfate and other monomers by micellar copolymerization. The forming time, rheology, swelling, mechanical properties and plugging properties of supramolecular gels were studied. The experimental results show that the formation time of supramolecular gel plugging agent is controllable, and it has excellent viscoelastic recovery ability in a certain range of shear strain and scanning frequency. When the compression amount is close to 88.3%, the compressive stress reaches 3.82 MPa. Meanwhile, the swelling performance of supramolecular gel was good, and the equilibrium swelling degree reached 22.1% after 188 min swelling in 15% NaCl brine solution. In 1% NaCl solution, the equilibrium swelling degree of supramolecular gel reached 32.5%. In addition, supramolecular gel has strong formation bonding ability, good plugging performance, plugging rate is greater than 95%, can effectively reduce the leakage and improve the plugging effect of low permeability layer. It is of reference and guiding significance for the long-term plugging of heterogeneous and malignant leakage formations.https://www.frontiersin.org/articles/10.3389/fchem.2024.1468766/fullsupramolecular gelsoil and gas drillingviscoelastic propertiesswelling propertiesplugging performance
spellingShingle Yongquan Han
Zhixue Yu
Zijun Guan
Rui Ma
Yuzhou Hu
Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
Frontiers in Chemistry
supramolecular gels
oil and gas drilling
viscoelastic properties
swelling properties
plugging performance
title Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
title_full Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
title_fullStr Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
title_full_unstemmed Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
title_short Hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
title_sort hydrophobic association supramolecular gel suitable for oil and gas drilling in fractured formation
topic supramolecular gels
oil and gas drilling
viscoelastic properties
swelling properties
plugging performance
url https://www.frontiersin.org/articles/10.3389/fchem.2024.1468766/full
work_keys_str_mv AT yongquanhan hydrophobicassociationsupramoleculargelsuitableforoilandgasdrillinginfracturedformation
AT zhixueyu hydrophobicassociationsupramoleculargelsuitableforoilandgasdrillinginfracturedformation
AT zijunguan hydrophobicassociationsupramoleculargelsuitableforoilandgasdrillinginfracturedformation
AT ruima hydrophobicassociationsupramoleculargelsuitableforoilandgasdrillinginfracturedformation
AT yuzhouhu hydrophobicassociationsupramoleculargelsuitableforoilandgasdrillinginfracturedformation