Tailoring Red-to-Blue Emission in In<sub>1−x</sub>Ga<sub>x</sub>P/ZnSe/ZnS Quantum Dots Using a Novel [In(btsa)<sub>2</sub>Cl]<sub>2</sub> Precursor and GaI<sub>3</sub>

Tailoring Red-to-Blue Emission in In<sub>1−x</sub>Ga<sub>x</sub>P/ZnSe/ZnS Quantum Dots Using a Novel [In(btsa)<sub>2</sub>Cl]<sub>2</sub> Precursor and GaI<sub>3</sub>

Ternary In<sub>1−x</sub>Ga<sub>x</sub>P quantum dots (QDs) have emerged as promising materials for efficient blue emission, owing to their tunable bandgap, high stability, and superior optoelectronic properties. However, most reported methods for Ga incorporation into the InP...

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Bibliographic Details
Main Authors: Calem Duah, Ji-Seoung Jeong, Ji Yeon Ryu, Bo Keun Park, Young Kuk Lee, Seon Joo Lee
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Molecules
Subjects:
quantum dots
In<sub>1−x</sub>Ga<sub>x</sub>P
In precursor
red-to-blue emission
photoluminescence quantum yield
Online Access:https://www.mdpi.com/1420-3049/30/1/35
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Summary:Ternary In<sub>1−x</sub>Ga<sub>x</sub>P quantum dots (QDs) have emerged as promising materials for efficient blue emission, owing to their tunable bandgap, high stability, and superior optoelectronic properties. However, most reported methods for Ga incorporation into the InP structure have predominantly relied on cation exchange in pre-grown InP QDs at elevated temperatures above 280 °C. This is largely due to the fact that, when heating In and P precursors in the presence of Ga, an InP/GaP core–shell structure readily forms. Herein, we introduce a novel synthesis approach using the indium precursor [In(btsa)<sub>2</sub>Cl]<sub>2</sub> and GaI<sub>3</sub> to fabricate In<sub>1−x</sub>Ga<sub>x</sub>P QDs in a single step at relatively low temperatures (200 °C). By adjusting the GaI<sub>3</sub> content, we achieved controlled emission tuning from red to blue. Structural and compositional analysis through X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) confirmed successful Ga<sup>3+</sup> incorporation into the QD core, with a corresponding blue shift in the emission as GaI<sub>3</sub> content increased. The synthesized QDs demonstrated a photoluminescence quantum yield (PLQY) of ~50% and a full width at half maximum (FWHM) of 45~62 nm, highlighting the potential of this synthesis method for advanced optoelectronic applications.
ISSN:1420-3049

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