Determination of solubility of chlorides of d-elements in chloroaluminate melts
Solubility of several transition metal chlorides (NiCl2, CrCl2, MoCl3, FeCl2) was measured in KCl-AlCl3 based melts. It was found that the solubility of studied metal chlorides depends on K : Al mole ratio. MoCl3 solubility decreases with increasing AlCl3 content. Solubility of CrCl2 and FeCl2 reach...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2014-09-01
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| Series: | Chimica Techno Acta |
| Subjects: | |
| Online Access: | https://chimicatechnoacta.ru/article/view/699 |
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| Summary: | Solubility of several transition metal chlorides (NiCl2, CrCl2, MoCl3, FeCl2) was measured in KCl-AlCl3 based melts. It was found that the solubility of studied metal chlorides depends on K : Al mole ratio. MoCl3 solubility decreases with increasing AlCl3 content. Solubility of CrCl2 and FeCl2 reaches maximum at K : Al ratio of 1 and decreases when this ratio either de-creases or increases. The dependence of NiCl2 solubility on K : Al mole ratio is V-shaped with the maximum near 0.9-0.95. The effect of temperature on solubility of transition metal chlorides in KCl-AlCl3 melts was also investigated. Increasing temperature does not alter the character of «solubility – K : Al mole ratio» dependences. |
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| ISSN: | 2411-1414 |