A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics

Cold-spray processing is a promising technique for the metallization of carbon fiber-reinforced plastics (CFRPs). However, the adhesion between the cold-sprayed metal deposits and CFRP substrate needs to be improved. In this study, a novel two-step strategy was developed to significantly enhance the...

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Main Authors: Jiayu Sun, Kenta Yamanaka, Chrystelle Bernard, Yuchao Lei, Shaoyun Zhou, Hao Lin, Kazuhiro Ogawa, Akihiko Chiba
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Materials & Design
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Online Access:http://www.sciencedirect.com/science/article/pii/S0264127524009432
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author Jiayu Sun
Kenta Yamanaka
Chrystelle Bernard
Yuchao Lei
Shaoyun Zhou
Hao Lin
Kazuhiro Ogawa
Akihiko Chiba
author_facet Jiayu Sun
Kenta Yamanaka
Chrystelle Bernard
Yuchao Lei
Shaoyun Zhou
Hao Lin
Kazuhiro Ogawa
Akihiko Chiba
author_sort Jiayu Sun
collection DOAJ
description Cold-spray processing is a promising technique for the metallization of carbon fiber-reinforced plastics (CFRPs). However, the adhesion between the cold-sprayed metal deposits and CFRP substrate needs to be improved. In this study, a novel two-step strategy was developed to significantly enhance the adhesion strength of cold-sprayed Sn/epoxy-based CFRP interfaces. The first step involved eroding the CFRP substrate at a high gas temperature (623 K) to artificially expose the carbon fibers at the surface. In the second step, Sn particles were deposited on the eroded CFRP substate at 523 K, forming a uniform coating. The exposed carbon fibers (CFs) serve as linkages and anchors at the Sn/CFRP interfaces, significantly enhancing the adhesion strength of the single-step Sn coating (∼2 MPa) to ∼ 6.25 MPa after three or more passes. A surface roughness of Sa ≈ 40 μm after the first step was optimal for enhancing the mechanical interlocking at the interfaces. These findings emphasize the importance of interfacial modification in enhancing the mechanical interlocking between the materials, which is crucial for the dominant adhesion mechanism, and suggest an effective strategy that can be applied in continuous cold-spray processing.
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publishDate 2025-01-01
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spelling doaj-art-bc5f4a00f3454577b4b8d2589aaa0c6e2025-01-09T06:12:27ZengElsevierMaterials & Design0264-12752025-01-01249113568A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plasticsJiayu Sun0Kenta Yamanaka1Chrystelle Bernard2Yuchao Lei3Shaoyun Zhou4Hao Lin5Kazuhiro Ogawa6Akihiko Chiba7Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan; Corresponding author.Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, 6-6-11 Aoba, Aramaki, Aoba-ku, Sendai 980-8579, Japan; Fracture and Reliability Research Institute, Tohoku University, 6-6-11 Aoba, Aramaki, Aoba-ku, Sendai 980-8579, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanFracture and Reliability Research Institute, Tohoku University, 6-6-11 Aoba, Aramaki, Aoba-ku, Sendai 980-8579, JapanFracture and Reliability Research Institute, Tohoku University, 6-6-11 Aoba, Aramaki, Aoba-ku, Sendai 980-8579, JapanFracture and Reliability Research Institute, Tohoku University, 6-6-11 Aoba, Aramaki, Aoba-ku, Sendai 980-8579, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan; New Industry Creation Hatchery Center, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanCold-spray processing is a promising technique for the metallization of carbon fiber-reinforced plastics (CFRPs). However, the adhesion between the cold-sprayed metal deposits and CFRP substrate needs to be improved. In this study, a novel two-step strategy was developed to significantly enhance the adhesion strength of cold-sprayed Sn/epoxy-based CFRP interfaces. The first step involved eroding the CFRP substrate at a high gas temperature (623 K) to artificially expose the carbon fibers at the surface. In the second step, Sn particles were deposited on the eroded CFRP substate at 523 K, forming a uniform coating. The exposed carbon fibers (CFs) serve as linkages and anchors at the Sn/CFRP interfaces, significantly enhancing the adhesion strength of the single-step Sn coating (∼2 MPa) to ∼ 6.25 MPa after three or more passes. A surface roughness of Sa ≈ 40 μm after the first step was optimal for enhancing the mechanical interlocking at the interfaces. These findings emphasize the importance of interfacial modification in enhancing the mechanical interlocking between the materials, which is crucial for the dominant adhesion mechanism, and suggest an effective strategy that can be applied in continuous cold-spray processing.http://www.sciencedirect.com/science/article/pii/S0264127524009432Carbon fiber-reinforced compositesMetallizationCold sprayingSurface treatments
spellingShingle Jiayu Sun
Kenta Yamanaka
Chrystelle Bernard
Yuchao Lei
Shaoyun Zhou
Hao Lin
Kazuhiro Ogawa
Akihiko Chiba
A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics
Materials & Design
Carbon fiber-reinforced composites
Metallization
Cold spraying
Surface treatments
title A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics
title_full A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics
title_fullStr A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics
title_full_unstemmed A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics
title_short A novel two-step process for enhancing adhesion strength of cold-spray metallization of carbon fiber-reinforced plastics
title_sort novel two step process for enhancing adhesion strength of cold spray metallization of carbon fiber reinforced plastics
topic Carbon fiber-reinforced composites
Metallization
Cold spraying
Surface treatments
url http://www.sciencedirect.com/science/article/pii/S0264127524009432
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