Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing

Abstract Micro-arc oxidation technology is one of the important means to improve the tribological properties of titanium alloys, but the bonding performance between the micro-arc oxidation film and the substrate material limits the further application of the micro-arc oxidation film. This study inve...

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Main Authors: Xin Ma, Qiang Shi, Yong Huang, Yaqi Liu, Xu Yue
Format: Article
Language:English
Published: Nature Portfolio 2025-03-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-89056-3
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author Xin Ma
Qiang Shi
Yong Huang
Yaqi Liu
Xu Yue
author_facet Xin Ma
Qiang Shi
Yong Huang
Yaqi Liu
Xu Yue
author_sort Xin Ma
collection DOAJ
description Abstract Micro-arc oxidation technology is one of the important means to improve the tribological properties of titanium alloys, but the bonding performance between the micro-arc oxidation film and the substrate material limits the further application of the micro-arc oxidation film. This study investigates TC4 titanium alloy as a model system, the microstructure and properties of the composite coating were obtained by laser surface texturing composite micro-arc oxidation process. The microstructure, phase composition, and worn morphology of the Micro-arc oxidation coating were characterized using X-ray diffraction, field emission scanning electron microscopy, and optical microscopy, respectively. Mechanical properties, including hardness, friction coefficient, and adhesion strength, were assessed using microhardness tester, Bruker tribometer, and micro/nano scratch tester, respectively. Results revealed that the Micro-arc oxidation coatings predominantly consist of Rutile TiO₂ and Anatase TiO₂ phases. The coating thickness in the mixed electrolyte reached up to 23.82 μm, with a maximum hardness of 467.56 HV₀.₅. Additionally, the friction coefficient of the laser-textured Micro-arc oxidation coatings decreased to 0.3. Laser surface texturing significantly enhanced the adhesion strength between the coating and substrate while simultaneously improving the tribological performance.
format Article
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institution Kabale University
issn 2045-2322
language English
publishDate 2025-03-01
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spelling doaj-art-bc19f858d7b44a41b138c20e690975ca2025-08-20T03:41:41ZengNature PortfolioScientific Reports2045-23222025-03-0115111110.1038/s41598-025-89056-3Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturingXin Ma0Qiang Shi1Yong Huang2Yaqi Liu3Xu Yue4College of Mechanical and Electrical Engineering, Xinjiang Institute of EngineeringCollege of Mechanical and Electrical Engineering, Xinjiang Institute of EngineeringCollege of Mechanical and Electrical Engineering, Xinjiang Institute of EngineeringCollege of Control Engineering, Xinjiang Institute of EngineeringXinjiang Xiangrun New Materials Technology Co., LtdAbstract Micro-arc oxidation technology is one of the important means to improve the tribological properties of titanium alloys, but the bonding performance between the micro-arc oxidation film and the substrate material limits the further application of the micro-arc oxidation film. This study investigates TC4 titanium alloy as a model system, the microstructure and properties of the composite coating were obtained by laser surface texturing composite micro-arc oxidation process. The microstructure, phase composition, and worn morphology of the Micro-arc oxidation coating were characterized using X-ray diffraction, field emission scanning electron microscopy, and optical microscopy, respectively. Mechanical properties, including hardness, friction coefficient, and adhesion strength, were assessed using microhardness tester, Bruker tribometer, and micro/nano scratch tester, respectively. Results revealed that the Micro-arc oxidation coatings predominantly consist of Rutile TiO₂ and Anatase TiO₂ phases. The coating thickness in the mixed electrolyte reached up to 23.82 μm, with a maximum hardness of 467.56 HV₀.₅. Additionally, the friction coefficient of the laser-textured Micro-arc oxidation coatings decreased to 0.3. Laser surface texturing significantly enhanced the adhesion strength between the coating and substrate while simultaneously improving the tribological performance.https://doi.org/10.1038/s41598-025-89056-3Titanium alloysLaser surface texturingMicro-arc oxidationMicrostructureProperties
spellingShingle Xin Ma
Qiang Shi
Yong Huang
Yaqi Liu
Xu Yue
Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing
Scientific Reports
Titanium alloys
Laser surface texturing
Micro-arc oxidation
Microstructure
Properties
title Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing
title_full Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing
title_fullStr Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing
title_full_unstemmed Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing
title_short Microstructure and properties of TC4 titanium alloy micro-arc oxide composite coating based on laser surface texturing
title_sort microstructure and properties of tc4 titanium alloy micro arc oxide composite coating based on laser surface texturing
topic Titanium alloys
Laser surface texturing
Micro-arc oxidation
Microstructure
Properties
url https://doi.org/10.1038/s41598-025-89056-3
work_keys_str_mv AT xinma microstructureandpropertiesoftc4titaniumalloymicroarcoxidecompositecoatingbasedonlasersurfacetexturing
AT qiangshi microstructureandpropertiesoftc4titaniumalloymicroarcoxidecompositecoatingbasedonlasersurfacetexturing
AT yonghuang microstructureandpropertiesoftc4titaniumalloymicroarcoxidecompositecoatingbasedonlasersurfacetexturing
AT yaqiliu microstructureandpropertiesoftc4titaniumalloymicroarcoxidecompositecoatingbasedonlasersurfacetexturing
AT xuyue microstructureandpropertiesoftc4titaniumalloymicroarcoxidecompositecoatingbasedonlasersurfacetexturing