Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub>
Objectives. Chalcogenides of transition elements with low oxidation states, as well as their substituted derivatives, remain a poorly studied class of chemical compounds. Rhenium disulfide has many distinctive features and great application potential as a new twodimensional semiconductor. This is du...
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MIREA - Russian Technological University
2024-07-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/2089 |
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| author | E. I. Efremova M. A. Lazov M. R. Kobrin V. V. Fomichev |
| author_facet | E. I. Efremova M. A. Lazov M. R. Kobrin V. V. Fomichev |
| author_sort | E. I. Efremova |
| collection | DOAJ |
| description | Objectives. Chalcogenides of transition elements with low oxidation states, as well as their substituted derivatives, remain a poorly studied class of chemical compounds. Rhenium disulfide has many distinctive features and great application potential as a new twodimensional semiconductor. This is due to its unusual structure and unique anisotropic properties. The presence of weak interlayer bonding and a unique distorted octahedral (1T) structure suggests the possibility of creating new phases on its basis. The aim of this work is to obtain and study phases in systems Re(IV)S2–Ti(IV)S2, Re(IV)S2–Mo(IV)S2, and Re(IV)S2–W(IV)S2.Methods. The samples were obtained by high-temperature solid-phase ampoule synthesis in a vacuum. The study was carried out using X-ray phase analysis and X-ray photoelectron spectroscopy.Results. The regions of existence of solid solutions, intercalates and two-phase regions in the resulting systems were established.Diffraction patterns were obtained for the new phases and the crystal lattice parameters were calculated. Based on data relating to the binding energies of core electrons with the nucleus, the study showed the valence states of the elements after synthesis. The study also confirmed that all phases obtained as a result of synthesis contain transition elements in the oxidation state (IV).Conclusions. Intercalated solid solutions are formed in areas rich in rhenium, while in areas close to titanium and molybdenum disulfides, intercalated phases are attained. In the ReS2–WS2 system there is a region of solid solutions, including 30, 50, and 70 mol % rhenium disulfide. Their structure is a polymorphic modification of the structure of the original components. The presence of rhenium, molybdenum, and tungsten in these phases in the oxidation state (+IV) was confirmed. The data obtained on phase formation in dichalcogenide systems can be practically used in the creation of materials with unique electronic, magnetic, and optical properties with a wide range of applications. |
| format | Article |
| id | doaj-art-ba93e43a5e9f472cba09abb0cfbc1734 |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2024-07-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-ba93e43a5e9f472cba09abb0cfbc17342025-08-20T03:56:32ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752024-07-0119325826610.32362/2410-6593-2024-19-3-258-2661764Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub>E. I. Efremova0M. A. Lazov1M. R. Kobrin2V. V. Fomichev3MIREA — Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)MIREA — Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)MIREA — Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)MIREA — Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)Objectives. Chalcogenides of transition elements with low oxidation states, as well as their substituted derivatives, remain a poorly studied class of chemical compounds. Rhenium disulfide has many distinctive features and great application potential as a new twodimensional semiconductor. This is due to its unusual structure and unique anisotropic properties. The presence of weak interlayer bonding and a unique distorted octahedral (1T) structure suggests the possibility of creating new phases on its basis. The aim of this work is to obtain and study phases in systems Re(IV)S2–Ti(IV)S2, Re(IV)S2–Mo(IV)S2, and Re(IV)S2–W(IV)S2.Methods. The samples were obtained by high-temperature solid-phase ampoule synthesis in a vacuum. The study was carried out using X-ray phase analysis and X-ray photoelectron spectroscopy.Results. The regions of existence of solid solutions, intercalates and two-phase regions in the resulting systems were established.Diffraction patterns were obtained for the new phases and the crystal lattice parameters were calculated. Based on data relating to the binding energies of core electrons with the nucleus, the study showed the valence states of the elements after synthesis. The study also confirmed that all phases obtained as a result of synthesis contain transition elements in the oxidation state (IV).Conclusions. Intercalated solid solutions are formed in areas rich in rhenium, while in areas close to titanium and molybdenum disulfides, intercalated phases are attained. In the ReS2–WS2 system there is a region of solid solutions, including 30, 50, and 70 mol % rhenium disulfide. Their structure is a polymorphic modification of the structure of the original components. The presence of rhenium, molybdenum, and tungsten in these phases in the oxidation state (+IV) was confirmed. The data obtained on phase formation in dichalcogenide systems can be practically used in the creation of materials with unique electronic, magnetic, and optical properties with a wide range of applications.https://www.finechem-mirea.ru/jour/article/view/2089solid solutionsintercalatestransition metal disulfidesphase formationcrystal latticebinding energies |
| spellingShingle | E. I. Efremova M. A. Lazov M. R. Kobrin V. V. Fomichev Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub> Тонкие химические технологии solid solutions intercalates transition metal disulfides phase formation crystal lattice binding energies |
| title | Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub> |
| title_full | Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub> |
| title_fullStr | Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub> |
| title_full_unstemmed | Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub> |
| title_short | Solid solutions in disulfide systems Re(IV)S<sub>2</sub>–Ti(IV)S<sub>2</sub>, Re(IV)S<sub>2</sub>–Mo(IV)S<sub>2</sub>, and Re(IV)S<sub>2</sub>–W(IV)S<sub>2</sub> |
| title_sort | solid solutions in disulfide systems re iv s sub 2 sub ti iv s sub 2 sub re iv s sub 2 sub mo iv s sub 2 sub and re iv s sub 2 sub w iv s sub 2 sub |
| topic | solid solutions intercalates transition metal disulfides phase formation crystal lattice binding energies |
| url | https://www.finechem-mirea.ru/jour/article/view/2089 |
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