Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders

Secondary raw materials, recycled Polypropylene (PP) and metal powders retrieved after use in the Powder Bed Fusion-Laser Beam process, are used to realize composite foams for microwave absorptance through chemical foaming. Morphological characterization allowed us to estimate foams’ relative densit...

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Main Authors: Valeria Marrocco, Rossella Surace, Elisabetta Brandonisio, Ilaria Marasco, Claudia Pagano, Cinzia Tonetti, Vito Errico, Giovanna Calò, Sabina L. Campanelli, Irene Fassi
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Materials & Design
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Online Access:http://www.sciencedirect.com/science/article/pii/S026412752500526X
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author Valeria Marrocco
Rossella Surace
Elisabetta Brandonisio
Ilaria Marasco
Claudia Pagano
Cinzia Tonetti
Vito Errico
Giovanna Calò
Sabina L. Campanelli
Irene Fassi
author_facet Valeria Marrocco
Rossella Surace
Elisabetta Brandonisio
Ilaria Marasco
Claudia Pagano
Cinzia Tonetti
Vito Errico
Giovanna Calò
Sabina L. Campanelli
Irene Fassi
author_sort Valeria Marrocco
collection DOAJ
description Secondary raw materials, recycled Polypropylene (PP) and metal powders retrieved after use in the Powder Bed Fusion-Laser Beam process, are used to realize composite foams for microwave absorptance through chemical foaming. Morphological characterization allowed us to estimate foams’ relative density, cell size, distribution, and circularity. The results highlighted that metal powders contributed to air cell nucleation during the process, thus influencing the final foam morphology. Then, numerical analyses were conducted on modeled PP foams to calculate Scattering (S) parameters and Shielding Effectiveness (SE), varying air cell areas, shapes, metal particle distribution, and evaluating their impacts on EM response. Based on simulation results, the S-parameters of all samples were then measured in the X-band. The calculated SE contributions, SER and SEA, showed that foams with virgin and reused metal powders behave very similarly. Finally, four samples foamed from extruded pellets were characterized morphologically and electromagnetically. The outcomes showed extruded-based foams had a slightly decreased relative density, increased air cell numbers with lower circularity, and better uniformity in the air cell distributions. Confronting SE contributions in the X-band, SEA improved by about 10%-20% compared to the mixed samples.
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spelling doaj-art-b9f15e95bef846b89080a1c46694c4d22025-08-20T03:46:41ZengElsevierMaterials & Design0264-12752025-06-0125411410610.1016/j.matdes.2025.114106Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powdersValeria Marrocco0Rossella Surace1Elisabetta Brandonisio2Ilaria Marasco3Claudia Pagano4Cinzia Tonetti5Vito Errico6Giovanna Calò7Sabina L. Campanelli8Irene Fassi9CNR-STIIMA Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, Via P. Lembo 38F, 70124 Bari, ItalyCNR-STIIMA Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, Via P. Lembo 38F, 70124 Bari, Italy; Corresponding author.CNR-STIIMA Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, Via P. Lembo 38F, 70124 Bari, ItalyPolitecnico di Bari, Department of Electric and Information Engineering, Via E. Orabona 4, 70126 Bari, ItalyCNR-STIIMA Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, Via A. Corti 12, 20133 Milano, ItalyCNR-STIIMA Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, Corso G. Pella 16, 13900 Biella, ItalyPolitecnico di Bari, Department of Mechanics, Mathematics and Management, Via E. Orabona 4, 70126 Bari, ItalyPolitecnico di Bari, Department of Electric and Information Engineering, Via E. Orabona 4, 70126 Bari, ItalyPolitecnico di Bari, Department of Mechanics, Mathematics and Management, Via E. Orabona 4, 70126 Bari, ItalyCNR-STIIMA Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, Via A. Corti 12, 20133 Milano, ItalySecondary raw materials, recycled Polypropylene (PP) and metal powders retrieved after use in the Powder Bed Fusion-Laser Beam process, are used to realize composite foams for microwave absorptance through chemical foaming. Morphological characterization allowed us to estimate foams’ relative density, cell size, distribution, and circularity. The results highlighted that metal powders contributed to air cell nucleation during the process, thus influencing the final foam morphology. Then, numerical analyses were conducted on modeled PP foams to calculate Scattering (S) parameters and Shielding Effectiveness (SE), varying air cell areas, shapes, metal particle distribution, and evaluating their impacts on EM response. Based on simulation results, the S-parameters of all samples were then measured in the X-band. The calculated SE contributions, SER and SEA, showed that foams with virgin and reused metal powders behave very similarly. Finally, four samples foamed from extruded pellets were characterized morphologically and electromagnetically. The outcomes showed extruded-based foams had a slightly decreased relative density, increased air cell numbers with lower circularity, and better uniformity in the air cell distributions. Confronting SE contributions in the X-band, SEA improved by about 10%-20% compared to the mixed samples.http://www.sciencedirect.com/science/article/pii/S026412752500526XRecycled polymersReused metal powdersFoaming processEMI shielding
spellingShingle Valeria Marrocco
Rossella Surace
Elisabetta Brandonisio
Ilaria Marasco
Claudia Pagano
Cinzia Tonetti
Vito Errico
Giovanna Calò
Sabina L. Campanelli
Irene Fassi
Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders
Materials & Design
Recycled polymers
Reused metal powders
Foaming process
EMI shielding
title Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders
title_full Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders
title_fullStr Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders
title_full_unstemmed Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders
title_short Investigating EMI shielding performance of recycled polypropylene (PP) composite foams with reused metal powders
title_sort investigating emi shielding performance of recycled polypropylene pp composite foams with reused metal powders
topic Recycled polymers
Reused metal powders
Foaming process
EMI shielding
url http://www.sciencedirect.com/science/article/pii/S026412752500526X
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