Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism

This paper investigated the use of magnesium phosphate cement (MPC) for solidifying sludge with different humic acid (HA) content (ranging from 0 to 4.5%) and explored the solidification mechanism. Fluidity, setting time, unconfined compressive strength (UCS), the strength formation mechanism, and t...

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Main Authors: Xiaoyi Yuan, Lei Peng, Bing Chen
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Journal of Rock Mechanics and Geotechnical Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S1674775524002968
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author Xiaoyi Yuan
Lei Peng
Bing Chen
author_facet Xiaoyi Yuan
Lei Peng
Bing Chen
author_sort Xiaoyi Yuan
collection DOAJ
description This paper investigated the use of magnesium phosphate cement (MPC) for solidifying sludge with different humic acid (HA) content (ranging from 0 to 4.5%) and explored the solidification mechanism. Fluidity, setting time, unconfined compressive strength (UCS), the strength formation mechanism, and the spontaneous imbibition process of solidified sludge (SS) were studied. The results indicate that MPC can be used as a low-alkalinity curing agent. As the HA content increases, fluidity and setting time also increase, while hydration temperature and strength decrease. Additionally, the failure mode of SS transitions from brittleness to ductility. The strength of SS is composed of the cementation strength provided by MPC hydration products, matric suction, osmotic suction, and the structural strength of the sludge. MPC reduces the structural strength caused by the shrinkage of pure sludge under the action of matric suction, but the incorporation of MPC significantly improved the strength when the sludge is eroded by water. X-ray diffraction (XRD) and scanning electron microscopy (SEM) show that the sludge and MPC can form a dense solid body, forming various hydration products, and synergistically improve the mechanical properties of the sludge.
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publishDate 2025-01-01
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series Journal of Rock Mechanics and Geotechnical Engineering
spelling doaj-art-b54207e2af4a44b795a03febcae5c0b02025-01-17T04:49:11ZengElsevierJournal of Rock Mechanics and Geotechnical Engineering1674-77552025-01-01171573585Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanismXiaoyi Yuan0Lei Peng1Bing Chen2Department of Civil Engineering, Shanghai Jiao Tong University, Shanghai, 200240, ChinaDepartment of Civil Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China; State Key Laboratory of Ocean Engineering, Shanghai Jiao Tong University, Shanghai, 200240, ChinaDepartment of Civil Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China; State Key Laboratory of Ocean Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China; Corresponding author. Department of Civil Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.This paper investigated the use of magnesium phosphate cement (MPC) for solidifying sludge with different humic acid (HA) content (ranging from 0 to 4.5%) and explored the solidification mechanism. Fluidity, setting time, unconfined compressive strength (UCS), the strength formation mechanism, and the spontaneous imbibition process of solidified sludge (SS) were studied. The results indicate that MPC can be used as a low-alkalinity curing agent. As the HA content increases, fluidity and setting time also increase, while hydration temperature and strength decrease. Additionally, the failure mode of SS transitions from brittleness to ductility. The strength of SS is composed of the cementation strength provided by MPC hydration products, matric suction, osmotic suction, and the structural strength of the sludge. MPC reduces the structural strength caused by the shrinkage of pure sludge under the action of matric suction, but the incorporation of MPC significantly improved the strength when the sludge is eroded by water. X-ray diffraction (XRD) and scanning electron microscopy (SEM) show that the sludge and MPC can form a dense solid body, forming various hydration products, and synergistically improve the mechanical properties of the sludge.http://www.sciencedirect.com/science/article/pii/S1674775524002968Sludge solidificationMPCUnsaturated spontaneous imbibitionStrength mechanismHumic acid
spellingShingle Xiaoyi Yuan
Lei Peng
Bing Chen
Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
Journal of Rock Mechanics and Geotechnical Engineering
Sludge solidification
MPC
Unsaturated spontaneous imbibition
Strength mechanism
Humic acid
title Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
title_full Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
title_fullStr Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
title_full_unstemmed Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
title_short Investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
title_sort investigation of magnesium phosphate cement on river dredged sludge with varying humic acid content and solidification mechanism
topic Sludge solidification
MPC
Unsaturated spontaneous imbibition
Strength mechanism
Humic acid
url http://www.sciencedirect.com/science/article/pii/S1674775524002968
work_keys_str_mv AT xiaoyiyuan investigationofmagnesiumphosphatecementonriverdredgedsludgewithvaryinghumicacidcontentandsolidificationmechanism
AT leipeng investigationofmagnesiumphosphatecementonriverdredgedsludgewithvaryinghumicacidcontentandsolidificationmechanism
AT bingchen investigationofmagnesiumphosphatecementonriverdredgedsludgewithvaryinghumicacidcontentandsolidificationmechanism