Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry
In this study we presented the preparation of eleven unknow in the literature surfactants based on mono- and disaccharides which contained urea bridge and 10, 12 or 14 carbon atoms in the hydrophobic chain in their structure. The surfactants were obtained in the SAW reaction in which CO2 is used as...
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| Format: | Article |
| Language: | English |
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Elsevier
2025-11-01
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| Series: | Journal of CO2 Utilization |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2212982025001842 |
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| author | Karolina Koselak Marcin Kozanecki Sławomir Kadłubowski Stanisław Porwański |
| author_facet | Karolina Koselak Marcin Kozanecki Sławomir Kadłubowski Stanisław Porwański |
| author_sort | Karolina Koselak |
| collection | DOAJ |
| description | In this study we presented the preparation of eleven unknow in the literature surfactants based on mono- and disaccharides which contained urea bridge and 10, 12 or 14 carbon atoms in the hydrophobic chain in their structure. The surfactants were obtained in the SAW reaction in which CO2 is used as one of the substrates with yields ranging from 16 % to 99 %. Some of the physicochemical properties were also investigated. The sugar derivatives are not soluble in water but shortening the hydrophobic chain to 8 carbon atoms increased their solubility. The HBL parameter indicated that the obtained surfactants are, among others, detergents, emulsifiers and wetting agents, which is also confirmed by results of the contact angle study. Compounds 29 forms aggregates or maybe even micelles above concentration of 1 mmol/l. The compounds also exhibit physical gel forming properties. |
| format | Article |
| id | doaj-art-b4f9508d4c1b4a7c9b284122d4cce4e5 |
| institution | Kabale University |
| issn | 2212-9839 |
| language | English |
| publishDate | 2025-11-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of CO2 Utilization |
| spelling | doaj-art-b4f9508d4c1b4a7c9b284122d4cce4e52025-08-26T04:14:15ZengElsevierJournal of CO2 Utilization2212-98392025-11-0110110320010.1016/j.jcou.2025.103200Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industryKarolina Koselak0Marcin Kozanecki1Sławomir Kadłubowski2Stanisław Porwański3Department of Organic and Applied Chemistry, University of Łódź, Tamka 12, Łódź 91-403, Poland; Corresponding authors.Department of Molecular Physics, Lodz University of Technology, Stefana Żeromskiego 114, Łódź 90-534, PolandInstitute of Applied Radiation Chemistry, Lodz University of Technology, Wróblewskiego 15, Łódź 93-590, PolandDepartment of Organic and Applied Chemistry, University of Łódź, Tamka 12, Łódź 91-403, Poland; Corresponding authors.In this study we presented the preparation of eleven unknow in the literature surfactants based on mono- and disaccharides which contained urea bridge and 10, 12 or 14 carbon atoms in the hydrophobic chain in their structure. The surfactants were obtained in the SAW reaction in which CO2 is used as one of the substrates with yields ranging from 16 % to 99 %. Some of the physicochemical properties were also investigated. The sugar derivatives are not soluble in water but shortening the hydrophobic chain to 8 carbon atoms increased their solubility. The HBL parameter indicated that the obtained surfactants are, among others, detergents, emulsifiers and wetting agents, which is also confirmed by results of the contact angle study. Compounds 29 forms aggregates or maybe even micelles above concentration of 1 mmol/l. The compounds also exhibit physical gel forming properties.http://www.sciencedirect.com/science/article/pii/S2212982025001842Carbon dioxideSAW ReactionSurfactantSaccharides |
| spellingShingle | Karolina Koselak Marcin Kozanecki Sławomir Kadłubowski Stanisław Porwański Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry Journal of CO2 Utilization Carbon dioxide SAW Reaction Surfactant Saccharides |
| title | Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry |
| title_full | Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry |
| title_fullStr | Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry |
| title_full_unstemmed | Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry |
| title_short | Carbon dioxide as a substrate in the Staudinger-aza-Wittig reaction leading to new sugar surfactants with potential use in cosmetics industry |
| title_sort | carbon dioxide as a substrate in the staudinger aza wittig reaction leading to new sugar surfactants with potential use in cosmetics industry |
| topic | Carbon dioxide SAW Reaction Surfactant Saccharides |
| url | http://www.sciencedirect.com/science/article/pii/S2212982025001842 |
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