SYNTHESIS AND CHARACTERIZATION OF AMINE(CHLOR0)COBALOXIME DERIVATIVES. APPROXIMATE VALUES OF THE ANGULAROVERLAP PARAMETER, ?, FOR THE COORDINATED AMINES
Four new complexes of the type [LCo ((DO)(DOH) pn) Cl] PF , where (DO) (DOH) pn = N , N '- propanediylbis (2, 3-butanedione2-imine3-oxirne)a nd L =morpholine (mrpln) (I), benzylamine (bzlan) (II), piperidine (pprdn)(III) and pyrrolidine (prldn) (IV) have been synthesized and characterized by e...
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
1996-09-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31117_1e0bae7c580317de0aa8a614d0fde12d.pdf |
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| Summary: | Four new complexes of the type [LCo ((DO)(DOH) pn) Cl] PF , where (DO)
(DOH) pn = N , N '- propanediylbis (2, 3-butanedione2-imine3-oxirne)a nd L =morpholine (mrpln) (I), benzylamine (bzlan) (II), piperidine (pprdn)(III) and pyrrolidine (prldn) (IV) have been synthesized and characterized by elemental analyses and spectroscopic methods. Approximate values of the angular-overlap parameter, ?, for the coordinated amines are estimated to be: 6395,6627,6797, and 7076 cm for mrpln, bzlan, pprdn, and prldn, respectively |
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| ISSN: | 1016-1104 2345-6914 |