The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding

Abstract Hsp90, a crucial molecular chaperone, regulates diverse client proteins, impacting both normal biology and disease. Central to its function is its conformational plasticity, driven by ATPase activity and client interactions. However, comprehensive insights into Hsp90’s dynamic molecular tra...

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Main Authors: Xiaozhan Qu, Simin Wang, Shuo Zhao, Chanjuan Wan, Weiya Xu, Chengdong Huang
Format: Article
Language:English
Published: Nature Portfolio 2024-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-55026-y
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author Xiaozhan Qu
Simin Wang
Shuo Zhao
Chanjuan Wan
Weiya Xu
Chengdong Huang
author_facet Xiaozhan Qu
Simin Wang
Shuo Zhao
Chanjuan Wan
Weiya Xu
Chengdong Huang
author_sort Xiaozhan Qu
collection DOAJ
description Abstract Hsp90, a crucial molecular chaperone, regulates diverse client proteins, impacting both normal biology and disease. Central to its function is its conformational plasticity, driven by ATPase activity and client interactions. However, comprehensive insights into Hsp90’s dynamic molecular transitions remain elusive. Using solution NMR spectroscopy, we reveal how ATP binding, hydrolysis, and client engagement drive conformational and dynamic shifts in E. coli Hsp90, HtpG, through its chaperone cycle. Pronounced conformational fluctuations occur, especially in regions crucial for nucleotide binding and conformational transitions. ATP binding induces slow-exchanging conformations, representing discrete on-path transition states from open to closed forms, while ATP hydrolysis shifts HtpG into a compact conformation. Client binding acts as an allosteric switch, dynamically priming HtpG for elevated chaperone activity and, therefore, its efficient remodeling. Here, we provide atomic-level insights into Hsp90’s functional mechanism, highlighting the interplay of conformation, dynamics, nucleotide, and client interactions.
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spelling doaj-art-b07cc6094f224bc68f9bb45b064c9b192024-12-15T12:10:00ZengNature PortfolioNature Communications2041-17232024-12-0115111210.1038/s41467-024-55026-yThe dynamic triage interplay of Hsp90 with its chaperone cycle and client bindingXiaozhan Qu0Simin Wang1Shuo Zhao2Chanjuan Wan3Weiya Xu4Chengdong Huang5MOE Key Laboratory for Cellular Dynamics, Center for Advanced Interdisciplinary Science and Biomedicine of IHM, Hefei National Laboratory for Physical Sciences at the Microscale, Biomedical Sciences and Health Laboratory of Anhui Province, Division of Life Sciences and Medicine, University of Science and Technology of ChinaMOE Key Laboratory for Cellular Dynamics, Center for Advanced Interdisciplinary Science and Biomedicine of IHM, Hefei National Laboratory for Physical Sciences at the Microscale, Biomedical Sciences and Health Laboratory of Anhui Province, Division of Life Sciences and Medicine, University of Science and Technology of ChinaMOE Key Laboratory for Cellular Dynamics, Center for Advanced Interdisciplinary Science and Biomedicine of IHM, Hefei National Laboratory for Physical Sciences at the Microscale, Biomedical Sciences and Health Laboratory of Anhui Province, Division of Life Sciences and Medicine, University of Science and Technology of ChinaMOE Key Laboratory for Cellular Dynamics, Center for Advanced Interdisciplinary Science and Biomedicine of IHM, Hefei National Laboratory for Physical Sciences at the Microscale, Biomedical Sciences and Health Laboratory of Anhui Province, Division of Life Sciences and Medicine, University of Science and Technology of ChinaMOE Key Laboratory for Cellular Dynamics, Center for Advanced Interdisciplinary Science and Biomedicine of IHM, Hefei National Laboratory for Physical Sciences at the Microscale, Biomedical Sciences and Health Laboratory of Anhui Province, Division of Life Sciences and Medicine, University of Science and Technology of ChinaMOE Key Laboratory for Cellular Dynamics, Center for Advanced Interdisciplinary Science and Biomedicine of IHM, Hefei National Laboratory for Physical Sciences at the Microscale, Biomedical Sciences and Health Laboratory of Anhui Province, Division of Life Sciences and Medicine, University of Science and Technology of ChinaAbstract Hsp90, a crucial molecular chaperone, regulates diverse client proteins, impacting both normal biology and disease. Central to its function is its conformational plasticity, driven by ATPase activity and client interactions. However, comprehensive insights into Hsp90’s dynamic molecular transitions remain elusive. Using solution NMR spectroscopy, we reveal how ATP binding, hydrolysis, and client engagement drive conformational and dynamic shifts in E. coli Hsp90, HtpG, through its chaperone cycle. Pronounced conformational fluctuations occur, especially in regions crucial for nucleotide binding and conformational transitions. ATP binding induces slow-exchanging conformations, representing discrete on-path transition states from open to closed forms, while ATP hydrolysis shifts HtpG into a compact conformation. Client binding acts as an allosteric switch, dynamically priming HtpG for elevated chaperone activity and, therefore, its efficient remodeling. Here, we provide atomic-level insights into Hsp90’s functional mechanism, highlighting the interplay of conformation, dynamics, nucleotide, and client interactions.https://doi.org/10.1038/s41467-024-55026-y
spellingShingle Xiaozhan Qu
Simin Wang
Shuo Zhao
Chanjuan Wan
Weiya Xu
Chengdong Huang
The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding
Nature Communications
title The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding
title_full The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding
title_fullStr The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding
title_full_unstemmed The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding
title_short The dynamic triage interplay of Hsp90 with its chaperone cycle and client binding
title_sort dynamic triage interplay of hsp90 with its chaperone cycle and client binding
url https://doi.org/10.1038/s41467-024-55026-y
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