Network topology and entropy analysis of tetragonal farneseite zeolites

Abstract Topological indices and their entropies of networks of complex materials and chemical structures are vital for quantitative structure activity and property relationship studies. Computing these measures for complex three-dimensional (3D) crystalline frameworks has been challenging owing to...

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Main Authors: Kavin Jacob, Joseph Clement, Micheal Arockiaraj, Pancras Peter, Krishnan Balasubramanian
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-90177-y
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author Kavin Jacob
Joseph Clement
Micheal Arockiaraj
Pancras Peter
Krishnan Balasubramanian
author_facet Kavin Jacob
Joseph Clement
Micheal Arockiaraj
Pancras Peter
Krishnan Balasubramanian
author_sort Kavin Jacob
collection DOAJ
description Abstract Topological indices and their entropies of networks of complex materials and chemical structures are vital for quantitative structure activity and property relationship studies. Computing these measures for complex three-dimensional (3D) crystalline frameworks has been challenging owing to their sizes and complexities. Tetragonal zeolite farneseite (FAR) is a mineral from the cancrinite sodalite group with potential applications in the field of microelectronics, medicine, environment, and industry. We have obtained generalized expressions for the various indices and entropies of these complex networks using a graph theoretical cut method to compute distance-based indices for the FAR framework. With the aid of computed indices and Shannon’s entropy formula, we explore the structural complexity of the frameworks. The present study reveals that the bond-wise entropies of sodalite (SOD) frameworks are greater compared to the farneseite-type frameworks which would have significant ramifications on phase transitions and other phenomena pertinent to such complex structures that typically undergo metamorphosis from one structural network topology to another complex network.
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spelling doaj-art-b001ff29b63945a89ea7f795e6695b852025-08-20T03:52:20ZengNature PortfolioScientific Reports2045-23222025-04-0115111410.1038/s41598-025-90177-yNetwork topology and entropy analysis of tetragonal farneseite zeolitesKavin Jacob0Joseph Clement1Micheal Arockiaraj2Pancras Peter3Krishnan Balasubramanian4Department of Mathematics, School of Advanced Sciences, Vellore Institute of TechnologyDepartment of Mathematics, School of Advanced Sciences, Vellore Institute of TechnologyDepartment of Mathematics, Loyola CollegeDepartment of Mathematics, School of Advanced Sciences, Vellore Institute of TechnologySchool of Molecular Sciences, Arizona State UniversityAbstract Topological indices and their entropies of networks of complex materials and chemical structures are vital for quantitative structure activity and property relationship studies. Computing these measures for complex three-dimensional (3D) crystalline frameworks has been challenging owing to their sizes and complexities. Tetragonal zeolite farneseite (FAR) is a mineral from the cancrinite sodalite group with potential applications in the field of microelectronics, medicine, environment, and industry. We have obtained generalized expressions for the various indices and entropies of these complex networks using a graph theoretical cut method to compute distance-based indices for the FAR framework. With the aid of computed indices and Shannon’s entropy formula, we explore the structural complexity of the frameworks. The present study reveals that the bond-wise entropies of sodalite (SOD) frameworks are greater compared to the farneseite-type frameworks which would have significant ramifications on phase transitions and other phenomena pertinent to such complex structures that typically undergo metamorphosis from one structural network topology to another complex network.https://doi.org/10.1038/s41598-025-90177-yDistance-based topologiesNetwork topology of phase transitionsSodalitesZeolite farneseiteSzeged-type entropies
spellingShingle Kavin Jacob
Joseph Clement
Micheal Arockiaraj
Pancras Peter
Krishnan Balasubramanian
Network topology and entropy analysis of tetragonal farneseite zeolites
Scientific Reports
Distance-based topologies
Network topology of phase transitions
Sodalites
Zeolite farneseite
Szeged-type entropies
title Network topology and entropy analysis of tetragonal farneseite zeolites
title_full Network topology and entropy analysis of tetragonal farneseite zeolites
title_fullStr Network topology and entropy analysis of tetragonal farneseite zeolites
title_full_unstemmed Network topology and entropy analysis of tetragonal farneseite zeolites
title_short Network topology and entropy analysis of tetragonal farneseite zeolites
title_sort network topology and entropy analysis of tetragonal farneseite zeolites
topic Distance-based topologies
Network topology of phase transitions
Sodalites
Zeolite farneseite
Szeged-type entropies
url https://doi.org/10.1038/s41598-025-90177-y
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AT pancraspeter networktopologyandentropyanalysisoftetragonalfarneseitezeolites
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