Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation

Anion exchange membrane electrolysis, which combines the advantages of both alkaline electrolysis and proton-exchange membrane electrolysis, is a promising technology to reduce the cost of hydrogen production. The present work focused on the study of the electrochemical phenomena of AEM electrolysis...

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Main Authors: Shing-Cheng Chang, Ru-En Gu, Yen-Hsin Chan
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/17/22/5682
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author Shing-Cheng Chang
Ru-En Gu
Yen-Hsin Chan
author_facet Shing-Cheng Chang
Ru-En Gu
Yen-Hsin Chan
author_sort Shing-Cheng Chang
collection DOAJ
description Anion exchange membrane electrolysis, which combines the advantages of both alkaline electrolysis and proton-exchange membrane electrolysis, is a promising technology to reduce the cost of hydrogen production. The present work focused on the study of the electrochemical phenomena of AEM electrolysis and the investigation of the key factors of the AEM hydrogen production system. The numerical model is established according to electrochemical reactions, polarization phenomena, and the power consumption of the balance of plant components of the system. The effects of operation parameters, including the temperature and hydrogen pressure of the electrolyzer, electrolyte concentration, and hydrogen supply pressure on the energy efficiency are studied. The basic electrochemical phenomena of AEM water electrolysis cells are analyzed by simulations of reversible potential and activation, and ohmic and concentration polarizations. The results reveal that increasing the operating temperature and hydrogen production pressure of the AEM electrolyzer has positive effects on the system’s efficiency. By conducting an optimization analysis of the electrolyzer temperature—which uses the heat energy generated by the electrochemical reaction of the electrolyzer to minimize the power consumption of the electrolyte pump and heater—the AEM system with an electrolyzer operating at 328 K and 30 bar can deliver hydrogen of pressure up to 200 bar under an energy efficiency of 56.4%.
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spelling doaj-art-af3591f9f6a247ee921edf8690d363da2024-11-26T18:02:19ZengMDPI AGEnergies1996-10732024-11-011722568210.3390/en17225682Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical SimulationShing-Cheng Chang0Ru-En Gu1Yen-Hsin Chan2Green Energy and Environment Research Laboratories, Industrial Technology Research Institute, Tainan 711, TaiwanDepartment of Mechanical and Computer-Aided Engineering, Feng Chia University, Taichung 407, TaiwanDepartment of Mechanical and Computer-Aided Engineering, Feng Chia University, Taichung 407, TaiwanAnion exchange membrane electrolysis, which combines the advantages of both alkaline electrolysis and proton-exchange membrane electrolysis, is a promising technology to reduce the cost of hydrogen production. The present work focused on the study of the electrochemical phenomena of AEM electrolysis and the investigation of the key factors of the AEM hydrogen production system. The numerical model is established according to electrochemical reactions, polarization phenomena, and the power consumption of the balance of plant components of the system. The effects of operation parameters, including the temperature and hydrogen pressure of the electrolyzer, electrolyte concentration, and hydrogen supply pressure on the energy efficiency are studied. The basic electrochemical phenomena of AEM water electrolysis cells are analyzed by simulations of reversible potential and activation, and ohmic and concentration polarizations. The results reveal that increasing the operating temperature and hydrogen production pressure of the AEM electrolyzer has positive effects on the system’s efficiency. By conducting an optimization analysis of the electrolyzer temperature—which uses the heat energy generated by the electrochemical reaction of the electrolyzer to minimize the power consumption of the electrolyte pump and heater—the AEM system with an electrolyzer operating at 328 K and 30 bar can deliver hydrogen of pressure up to 200 bar under an energy efficiency of 56.4%.https://www.mdpi.com/1996-1073/17/22/5682water electrolysishydrogen productionthermodynamic analysis
spellingShingle Shing-Cheng Chang
Ru-En Gu
Yen-Hsin Chan
Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
Energies
water electrolysis
hydrogen production
thermodynamic analysis
title Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
title_full Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
title_fullStr Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
title_full_unstemmed Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
title_short Parameter Analysis of Anion Exchange Membrane Water Electrolysis System by Numerical Simulation
title_sort parameter analysis of anion exchange membrane water electrolysis system by numerical simulation
topic water electrolysis
hydrogen production
thermodynamic analysis
url https://www.mdpi.com/1996-1073/17/22/5682
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AT ruengu parameteranalysisofanionexchangemembranewaterelectrolysissystembynumericalsimulation
AT yenhsinchan parameteranalysisofanionexchangemembranewaterelectrolysissystembynumericalsimulation