catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands
In the title compound, diphenyltin(IV) diisothiocyanate, [Sn(NCS)2(C6H5)2]n or Ph2Sn(NCS)2, comparatively long tin–nitrogen and short tin–sulfur bonds prove that the ambidentate isothiocyanate ion acts as a bridge between two neighboring, octahedrally coordinated tin atoms. As a result, the molecule...
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International Union of Crystallography
2024-11-01
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| Online Access: | https://journals.iucr.org/paper?S2414314624010939 |
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| author | Ann-Kathrin Pancratz Anne Kamrowski Hans Reuter |
| author_facet | Ann-Kathrin Pancratz Anne Kamrowski Hans Reuter |
| author_sort | Ann-Kathrin Pancratz |
| collection | DOAJ |
| description | In the title compound, diphenyltin(IV) diisothiocyanate, [Sn(NCS)2(C6H5)2]n or Ph2Sn(NCS)2, comparatively long tin–nitrogen and short tin–sulfur bonds prove that the ambidentate isothiocyanate ion acts as a bridge between two neighboring, octahedrally coordinated tin atoms. As a result, the molecules lose their individuality in favor of a layered coordination polymer that represents a new type of molecular interactions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion. |
| format | Article |
| id | doaj-art-a98aba00b17146b7a4d33a82d9b84e11 |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-a98aba00b17146b7a4d33a82d9b84e112024-12-05T11:43:19ZengInternational Union of CrystallographyIUCrData2414-31462024-11-01911x24109310.1107/S2414314624010939tk4112catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligandsAnn-Kathrin Pancratz0Anne Kamrowski1Hans Reuter2Chemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, GermanyChemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, GermanyChemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, GermanyIn the title compound, diphenyltin(IV) diisothiocyanate, [Sn(NCS)2(C6H5)2]n or Ph2Sn(NCS)2, comparatively long tin–nitrogen and short tin–sulfur bonds prove that the ambidentate isothiocyanate ion acts as a bridge between two neighboring, octahedrally coordinated tin atoms. As a result, the molecules lose their individuality in favor of a layered coordination polymer that represents a new type of molecular interactions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.https://journals.iucr.org/paper?S2414314624010939crystal structureisothiocyanatediphenyltinlayer structure |
| spellingShingle | Ann-Kathrin Pancratz Anne Kamrowski Hans Reuter catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands IUCrData crystal structure isothiocyanate diphenyltin layer structure |
| title | catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands |
| title_full | catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands |
| title_fullStr | catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands |
| title_full_unstemmed | catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands |
| title_short | catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands |
| title_sort | catena poly diphenyltin iv di μ isothiocyanato an unprecedented layered coordination polymer resulting from bridging κ2n s thiocyanato ligands |
| topic | crystal structure isothiocyanate diphenyltin layer structure |
| url | https://journals.iucr.org/paper?S2414314624010939 |
| work_keys_str_mv | AT annkathrinpancratz catenapolydiphenyltinivdimisothiocyanatoanunprecedentedlayeredcoordinationpolymerresultingfrombridgingk2nsthiocyanatoligands AT annekamrowski catenapolydiphenyltinivdimisothiocyanatoanunprecedentedlayeredcoordinationpolymerresultingfrombridgingk2nsthiocyanatoligands AT hansreuter catenapolydiphenyltinivdimisothiocyanatoanunprecedentedlayeredcoordinationpolymerresultingfrombridgingk2nsthiocyanatoligands |