catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands
In the title compound, diphenyltin(IV) diisothiocyanate, [Sn(NCS)2(C6H5)2]n or Ph2Sn(NCS)2, comparatively long tin–nitrogen and short tin–sulfur bonds prove that the ambidentate isothiocyanate ion acts as a bridge between two neighboring, octahedrally coordinated tin atoms. As a result, the molecule...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2024-11-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2414314624010939 |
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| Summary: | In the title compound, diphenyltin(IV) diisothiocyanate, [Sn(NCS)2(C6H5)2]n or Ph2Sn(NCS)2, comparatively long tin–nitrogen and short tin–sulfur bonds prove that the ambidentate isothiocyanate ion acts as a bridge between two neighboring, octahedrally coordinated tin atoms. As a result, the molecules lose their individuality in favor of a layered coordination polymer that represents a new type of molecular interactions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion. |
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| ISSN: | 2414-3146 |