Intrinsically Flame‐Retardant Polyamide 6 by Anionic Ring‐Opening Copolymerization with a Phosphorous‐Containing Comonomer

Intrinsically Flame‐Retardant Polyamide 6 by Anionic Ring‐Opening Copolymerization with a Phosphorous‐Containing Comonomer

Abstract A three‐step synthetic route is established for the synthesis of a phosphorus‐containing ε‐caprolactam derivative, starting from cyclohex‐2‐enone and diphenylphosphinous chloride, followed by a Beckmann rearrangement. 2D NMR spectroscopy reveals that the phosphorus moiety is selectively loc...

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Main Authors: Carlo Pani, Hagen J. Altmann, Patrick Probst, Iris Elser, Mark Steinmann, Simon König, Philipp Kreis, Lisa Kuske, Dominik Weidich, Anke Gähr, Jonas Groos, Julian Kappler, Janis Musso, Dongren Wang, Michael R. Buchmeiser
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:Macromolecular Materials and Engineering
Subjects:
cast polyamide 6
flame retardant
latent
Online Access:https://doi.org/10.1002/mame.202400253
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