Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt

BaZr1-xYxO3-δ (x = 0, 0.04, 0.08, 0.12) crucibles with doping different contents of Y2O3 were prepared by the pressureless sintering method, and the interfacial reaction behaviors in TiAl alloy melt was investigated using vacuum induction melting. The results revealed that the BaZrO3 ceramics contai...

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Main Authors: Yun Shen, Du Hong, Tianfang Sun, Rui Hou, Gong Zheng, Yaran Niu, Guang Chen
Format: Article
Language:English
Published: Taylor & Francis Group 2025-01-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/21870764.2024.2447623
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author Yun Shen
Du Hong
Tianfang Sun
Rui Hou
Gong Zheng
Yaran Niu
Guang Chen
author_facet Yun Shen
Du Hong
Tianfang Sun
Rui Hou
Gong Zheng
Yaran Niu
Guang Chen
author_sort Yun Shen
collection DOAJ
description BaZr1-xYxO3-δ (x = 0, 0.04, 0.08, 0.12) crucibles with doping different contents of Y2O3 were prepared by the pressureless sintering method, and the interfacial reaction behaviors in TiAl alloy melt was investigated using vacuum induction melting. The results revealed that the BaZrO3 ceramics contained a small amount of monoclinic ZrO2 and Ba-rich areas. With increasing Y2O3 doping content, yttrium-rich cubic ZrO2 instead of monoclinic ZrO2 generated and the average grain size decreased significantly. The results after melting showed that the thickness of the reaction layer of the BaZr1-xYxO3-δ decreased from hundreds of microns to tens of microns with the increase of the Y2O3 content. Moreover, the zirconium content in the alloy decreased. Overall, the BaZr0.96Y0.04O3-δ ceramic crucible had a small thickness of the reaction layer and slight oxygen contamination in the alloys. This study offers new insights for the further development of Y2O3-doped BaZrO3 ceramics used in melting TiAl alloys.
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institution Kabale University
issn 2187-0764
language English
publishDate 2025-01-01
publisher Taylor & Francis Group
record_format Article
series Journal of Asian Ceramic Societies
spelling doaj-art-a8ba45fbacee4afb8a1a5694a14460952025-01-09T12:40:28ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642025-01-0111210.1080/21870764.2024.2447623Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy meltYun Shen0Du Hong1Tianfang Sun2Rui Hou3Gong Zheng4Yaran Niu5Guang Chen6Jiangsu Belight Laboratory, State Key Laboratory of Advanced Casting Technology, Nanjing University of Science and Technology, Nanjing, ChinaKey Laboratory of Inorganic Coating Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaJiangsu Belight Laboratory, State Key Laboratory of Advanced Casting Technology, Nanjing University of Science and Technology, Nanjing, ChinaJiangsu Belight Laboratory, State Key Laboratory of Advanced Casting Technology, Nanjing University of Science and Technology, Nanjing, ChinaJiangsu Belight Laboratory, State Key Laboratory of Advanced Casting Technology, Nanjing University of Science and Technology, Nanjing, ChinaKey Laboratory of Inorganic Coating Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, ChinaJiangsu Belight Laboratory, State Key Laboratory of Advanced Casting Technology, Nanjing University of Science and Technology, Nanjing, ChinaBaZr1-xYxO3-δ (x = 0, 0.04, 0.08, 0.12) crucibles with doping different contents of Y2O3 were prepared by the pressureless sintering method, and the interfacial reaction behaviors in TiAl alloy melt was investigated using vacuum induction melting. The results revealed that the BaZrO3 ceramics contained a small amount of monoclinic ZrO2 and Ba-rich areas. With increasing Y2O3 doping content, yttrium-rich cubic ZrO2 instead of monoclinic ZrO2 generated and the average grain size decreased significantly. The results after melting showed that the thickness of the reaction layer of the BaZr1-xYxO3-δ decreased from hundreds of microns to tens of microns with the increase of the Y2O3 content. Moreover, the zirconium content in the alloy decreased. Overall, the BaZr0.96Y0.04O3-δ ceramic crucible had a small thickness of the reaction layer and slight oxygen contamination in the alloys. This study offers new insights for the further development of Y2O3-doped BaZrO3 ceramics used in melting TiAl alloys.https://www.tandfonline.com/doi/10.1080/21870764.2024.2447623Barium zirconate ceramicsY2O3-dopedTiAlInterfacial reaction
spellingShingle Yun Shen
Du Hong
Tianfang Sun
Rui Hou
Gong Zheng
Yaran Niu
Guang Chen
Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt
Journal of Asian Ceramic Societies
Barium zirconate ceramics
Y2O3-doped
TiAl
Interfacial reaction
title Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt
title_full Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt
title_fullStr Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt
title_full_unstemmed Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt
title_short Effects of yttria doping on the interfacial reaction between barium zirconate ceramics and TiAl alloy melt
title_sort effects of yttria doping on the interfacial reaction between barium zirconate ceramics and tial alloy melt
topic Barium zirconate ceramics
Y2O3-doped
TiAl
Interfacial reaction
url https://www.tandfonline.com/doi/10.1080/21870764.2024.2447623
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