Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups
Porous microspheres of glycidyl methacrylate cross-linked with trimethylolpropane trimethacrylate were prepared with toluene as porogen by suspension–emulsion polymerization. With increasing molar ratio of the functional monomer to cross-linker, the epoxy group content increases significantly, where...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2015-08-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.33.6-8.617 |
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| author | Małgorzata Maciejewska Yuliia M. Bolbukh |
| author_facet | Małgorzata Maciejewska Yuliia M. Bolbukh |
| author_sort | Małgorzata Maciejewska |
| collection | DOAJ |
| description | Porous microspheres of glycidyl methacrylate cross-linked with trimethylolpropane trimethacrylate were prepared with toluene as porogen by suspension–emulsion polymerization. With increasing molar ratio of the functional monomer to cross-linker, the epoxy group content increases significantly, whereas the parameters of porous structure (specific surface area and total pore volume) decrease. To obtain adsorbents bearing functional groups, the porous methacrylate network was modified by subsequent treatment with diethylenetriamine. Polymers capacity towards Cu(II), Zn(II), Pb(II) and Cd(II) was investigated. |
| format | Article |
| id | doaj-art-a3c545a5c44b4c0e84041d6b8afaa5fd |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2015-08-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-a3c545a5c44b4c0e84041d6b8afaa5fd2025-01-02T23:11:47ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382015-08-013310.1260/0263-6174.33.6-8.617Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine GroupsMałgorzata Maciejewska0Yuliia M. Bolbukh1Faculty of Chemistry, Maria Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 3, 20-031 Lublin, Poland.Institute of Surface Chemistry of National Academy of Science, 17 General Naumov Strasse, 03164 Kiev, Ukraine.Porous microspheres of glycidyl methacrylate cross-linked with trimethylolpropane trimethacrylate were prepared with toluene as porogen by suspension–emulsion polymerization. With increasing molar ratio of the functional monomer to cross-linker, the epoxy group content increases significantly, whereas the parameters of porous structure (specific surface area and total pore volume) decrease. To obtain adsorbents bearing functional groups, the porous methacrylate network was modified by subsequent treatment with diethylenetriamine. Polymers capacity towards Cu(II), Zn(II), Pb(II) and Cd(II) was investigated.https://doi.org/10.1260/0263-6174.33.6-8.617 |
| spellingShingle | Małgorzata Maciejewska Yuliia M. Bolbukh Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups Adsorption Science & Technology |
| title | Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups |
| title_full | Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups |
| title_fullStr | Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups |
| title_full_unstemmed | Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups |
| title_short | Study on Synthesis and Characterization of Porous Microspheres with Pendant Amine Groups |
| title_sort | study on synthesis and characterization of porous microspheres with pendant amine groups |
| url | https://doi.org/10.1260/0263-6174.33.6-8.617 |
| work_keys_str_mv | AT małgorzatamaciejewska studyonsynthesisandcharacterizationofporousmicrosphereswithpendantaminegroups AT yuliiambolbukh studyonsynthesisandcharacterizationofporousmicrosphereswithpendantaminegroups |