Discriminating Analysis of Metal Ions via Multivariate Curve Resolution–Alternating Least Squares Applied to Silver Nanoparticle Sensor

Heavy metals are life-threatening pollutions because of their great toxicity, long-term persistence in nature and their bioaccumulation in living organisms. In this work, we performed multivariate curve resolution–alternating least squares analysis of UV-Vis raw spectra received by a colorimetric se...

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Bibliographic Details
Main Authors: Andrea Rossi, Massimiliano Cuccioloni, Francesco Pellegrino, Rita Giovannetti, Eugenio Alladio
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/1/57
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Summary:Heavy metals are life-threatening pollutions because of their great toxicity, long-term persistence in nature and their bioaccumulation in living organisms. In this work, we performed multivariate curve resolution–alternating least squares analysis of UV-Vis raw spectra received by a colorimetric sensor constructed on mercaptoundecanoic acid functionalized silver nanoparticles (AgNPs@11MUA) to detect Cd<sup>2+</sup>, Cu<sup>2+</sup>, Mn<sup>2+</sup>, Ni<sup>2+</sup>, and Zn<sup>2+</sup> in water. This combined approach allowed the rapid identification and quantification of multiple heavy metals and showed adequate sensitivity and selectivity, thus representing a promising analytical and computational method for both laboratory and field applications such as environmental safety and public health monitoring.
ISSN:2079-4991