Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy

Micro-nano plastics (MNPs) have become pervasive throughout the environment and emerged as significant pollutants, posing a potential threat to the natural environment and human health. Nonetheless, there remains a technological gap in the accurate analysis of trace and small-size MNPs in the enviro...

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Main Authors: Hao Liu, Hui Liang, Siyuan Zheng, Rui Hu, Wenqiang Pei, Le Wang, Yongchao Lai
Format: Article
Language:English
Published: Elsevier 2025-12-01
Series:Sensors and Actuators Reports
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666053925000943
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author Hao Liu
Hui Liang
Siyuan Zheng
Rui Hu
Wenqiang Pei
Le Wang
Yongchao Lai
author_facet Hao Liu
Hui Liang
Siyuan Zheng
Rui Hu
Wenqiang Pei
Le Wang
Yongchao Lai
author_sort Hao Liu
collection DOAJ
description Micro-nano plastics (MNPs) have become pervasive throughout the environment and emerged as significant pollutants, posing a potential threat to the natural environment and human health. Nonetheless, there remains a technological gap in the accurate analysis of trace and small-size MNPs in the environment. This study proposes a refined strategy for sample pretreatment and surface-enhanced Raman spectroscopy (SERS) analysis of MNPs in a water environment. MNPs were initially captured from the matrix using filter membranes, and subsequently released using an appropriate solvent. This approach not only separated the MNPs from the matrix and impurities, but also allowed the irregular and rigid MNPs to fit the surface of the KI-modified SERS substrates. This SERS-based approach facilitates the analysis of polystyrene (PS) MNPs of varying sizes at a concentration of 0.05 ng/mL across multiple water matrices. Furthermore, PS MNPs released from disposable cups were found using this method in everyday life. This simple and highly efficient strategy is ideal for the analyzing MNPs in everyday life and has the potential to facilitate future research on MNPs in the environment and their impact on human health.
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issn 2666-0539
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publishDate 2025-12-01
publisher Elsevier
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series Sensors and Actuators Reports
spelling doaj-art-a37f22f5bcdd45409571b3967a8a831c2025-08-25T04:14:48ZengElsevierSensors and Actuators Reports2666-05392025-12-011010037610.1016/j.snr.2025.100376Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategyHao Liu0Hui Liang1Siyuan Zheng2Rui Hu3Wenqiang Pei4Le Wang5Yongchao Lai6Medical Science and Technology Innovation Center, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, ChinaSchool of Pharmaceutical Sciences & Institute of Materia Medica, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, China,Medical Science and Technology Innovation Center, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, ChinaMedical Science and Technology Innovation Center, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, ChinaSchool of Chinese Materia Medica, Nanjing University of Chinese Medicine, Nanjing 210023, ChinaTechnical Center of Jinan Customs, Jinan, 250014, China; Corresponding authors.School of Public Health, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan 250117, China; Corresponding authors.Micro-nano plastics (MNPs) have become pervasive throughout the environment and emerged as significant pollutants, posing a potential threat to the natural environment and human health. Nonetheless, there remains a technological gap in the accurate analysis of trace and small-size MNPs in the environment. This study proposes a refined strategy for sample pretreatment and surface-enhanced Raman spectroscopy (SERS) analysis of MNPs in a water environment. MNPs were initially captured from the matrix using filter membranes, and subsequently released using an appropriate solvent. This approach not only separated the MNPs from the matrix and impurities, but also allowed the irregular and rigid MNPs to fit the surface of the KI-modified SERS substrates. This SERS-based approach facilitates the analysis of polystyrene (PS) MNPs of varying sizes at a concentration of 0.05 ng/mL across multiple water matrices. Furthermore, PS MNPs released from disposable cups were found using this method in everyday life. This simple and highly efficient strategy is ideal for the analyzing MNPs in everyday life and has the potential to facilitate future research on MNPs in the environment and their impact on human health.http://www.sciencedirect.com/science/article/pii/S2666053925000943Micro-nano plastics (MNPs)Surface-enhanced Raman spectroscopy (SERS)Filtrationsuitable solventDrinking water
spellingShingle Hao Liu
Hui Liang
Siyuan Zheng
Rui Hu
Wenqiang Pei
Le Wang
Yongchao Lai
Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy
Sensors and Actuators Reports
Micro-nano plastics (MNPs)
Surface-enhanced Raman spectroscopy (SERS)
Filtration
suitable solvent
Drinking water
title Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy
title_full Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy
title_fullStr Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy
title_full_unstemmed Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy
title_short Straightforward and sensitive detection of micro-nano plastics with surface-enhanced Raman spectroscopy by the filtration-dissolution- adsorption strategy
title_sort straightforward and sensitive detection of micro nano plastics with surface enhanced raman spectroscopy by the filtration dissolution adsorption strategy
topic Micro-nano plastics (MNPs)
Surface-enhanced Raman spectroscopy (SERS)
Filtration
suitable solvent
Drinking water
url http://www.sciencedirect.com/science/article/pii/S2666053925000943
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