Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes

The regularities of the formation of ion-plasma coatings of Ti‑W‑B system and the impact of postcondensation treatment on their phase composition, structure, substructure and stress state. It is shown that at a low content of Ti‑component (up to 2 at.% ) two-phase state from β‑WB‑ and (Ti, W)B2‑ pha...

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Main Authors: O.A. Shovkoplyas, O.V. Sobol
Format: Article
Language:English
Published: Sumy State University 2014-06-01
Series:Журнал нано- та електронної фізики
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Online Access:http://jnep.sumdu.edu.ua/download/numbers/2014/2/articles/jnep_2014_V6_02024.pdf
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author O.A. Shovkoplyas
O.V. Sobol
author_facet O.A. Shovkoplyas
O.V. Sobol
author_sort O.A. Shovkoplyas
collection DOAJ
description The regularities of the formation of ion-plasma coatings of Ti‑W‑B system and the impact of postcondensation treatment on their phase composition, structure, substructure and stress state. It is shown that at a low content of Ti‑component (up to 2 at.% ) two-phase state from β‑WB‑ and (Ti, W)B2‑ phases is formed. Annealing at 1270 K leads to the grain growth of the β‑WB‑phase mainly. When the content of Ti is more than 5 at.%, a single-phase (Ti, W)B2 state of the coating is formed. Structure and substructural characteristics of these coatings are stable at annealing and proton irradiation with the energy of 200 keV up to the dose of 6,5×1017 cm–2. Influence of thermal-radiation exposure affects the change of the stress-strain state (relaxation of compressive strain). The observed changes are explained on the basis of minimizing the free energy of the system.
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issn 2077-6772
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publishDate 2014-06-01
publisher Sumy State University
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series Журнал нано- та електронної фізики
spelling doaj-art-a2550251f997436f9b1ecb1b83d3e3d52025-08-20T03:38:43ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722014-06-016202024-102024-6Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic FluxesO.A. Shovkoplyas0O.V. Sobol1Sumy State University, 2, Rimsky Korsakov Str., 40007 Sumy, UkraineNational Technical University “KhPI", 21, Frunze Str., 61002 Kharkiv, UkraineThe regularities of the formation of ion-plasma coatings of Ti‑W‑B system and the impact of postcondensation treatment on their phase composition, structure, substructure and stress state. It is shown that at a low content of Ti‑component (up to 2 at.% ) two-phase state from β‑WB‑ and (Ti, W)B2‑ phases is formed. Annealing at 1270 K leads to the grain growth of the β‑WB‑phase mainly. When the content of Ti is more than 5 at.%, a single-phase (Ti, W)B2 state of the coating is formed. Structure and substructural characteristics of these coatings are stable at annealing and proton irradiation with the energy of 200 keV up to the dose of 6,5×1017 cm–2. Influence of thermal-radiation exposure affects the change of the stress-strain state (relaxation of compressive strain). The observed changes are explained on the basis of minimizing the free energy of the system.http://jnep.sumdu.edu.ua/download/numbers/2014/2/articles/jnep_2014_V6_02024.pdfIon-plasma coatingsIrradiationX-ray diffraction studiesAnnealingSeparation of complex profile
spellingShingle O.A. Shovkoplyas
O.V. Sobol
Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes
Журнал нано- та електронної фізики
Ion-plasma coatings
Irradiation
X-ray diffraction studies
Annealing
Separation of complex profile
title Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes
title_full Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes
title_fullStr Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes
title_full_unstemmed Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes
title_short Influence of Thermal and Radiation Effects on the Phase Composition, Structure and Stress-Strain State of Ti-W-B System Coatings Deposited from Ion-atomic Fluxes
title_sort influence of thermal and radiation effects on the phase composition structure and stress strain state of ti w b system coatings deposited from ion atomic fluxes
topic Ion-plasma coatings
Irradiation
X-ray diffraction studies
Annealing
Separation of complex profile
url http://jnep.sumdu.edu.ua/download/numbers/2014/2/articles/jnep_2014_V6_02024.pdf
work_keys_str_mv AT oashovkoplyas influenceofthermalandradiationeffectsonthephasecompositionstructureandstressstrainstateoftiwbsystemcoatingsdepositedfromionatomicfluxes
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