Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries
Polyanion-based materials are considered one of the most attractive and promising cathode materials for lithium-ion batteries (LIBs) due to their good stability, safety, cost-effectiveness, suitable voltages, and minimal environmental impact. However, these materials suffer from poor rate capability...
Saved in:
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2024-10-01
|
| Series: | Nano Materials Science |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2589965124000047 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1846151054630060032 |
|---|---|
| author | Sajeela Awasthi Srikanta Moharana Vaneet Kumar Nannan Wang Elham Chmanehpour Anupam Deep Sharma Santosh K. Tiwari Vijay Kumar Yogendra Kumar Mishra |
| author_facet | Sajeela Awasthi Srikanta Moharana Vaneet Kumar Nannan Wang Elham Chmanehpour Anupam Deep Sharma Santosh K. Tiwari Vijay Kumar Yogendra Kumar Mishra |
| author_sort | Sajeela Awasthi |
| collection | DOAJ |
| description | Polyanion-based materials are considered one of the most attractive and promising cathode materials for lithium-ion batteries (LIBs) due to their good stability, safety, cost-effectiveness, suitable voltages, and minimal environmental impact. However, these materials suffer from poor rate capability and low-temperature performance owing to limited electronic and ionic conductivity, which restricts their practical applicability. Recent developments, such as coating material particles with carbon or a conductive polymer, crystal deformation through the doping of foreign metal ions, and the production of nanostructured materials, have significantly enhanced the electrochemical performances of these materials. The successful applications of polyanion-based materials, especially in lithium-ion batteries, have been extensively reported. This comprehensive review discusses the current progress in crystal deformation in polyanion-based cathode materials, including phosphates, fluorophosphates, pyrophosphates, borates, silicates, sulfates, fluorosilicates, and oxalates. Therefore, this review provides detailed discussions on their synthesis strategies, electrochemical performance, and the doping of various ions. |
| format | Article |
| id | doaj-art-a1cc9abe43ba4d1aa58be5766e731e6d |
| institution | Kabale University |
| issn | 2589-9651 |
| language | English |
| publishDate | 2024-10-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Nano Materials Science |
| spelling | doaj-art-a1cc9abe43ba4d1aa58be5766e731e6d2024-11-28T04:34:56ZengKeAi Communications Co., Ltd.Nano Materials Science2589-96512024-10-0165504535Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteriesSajeela Awasthi0Srikanta Moharana1Vaneet Kumar2Nannan Wang3Elham Chmanehpour4Anupam Deep Sharma5Santosh K. Tiwari6Vijay Kumar7Yogendra Kumar Mishra8Department of Applied Sciences, CT Institute of Engineering, Management and Technology, CT Group of Institutions, Shahpur, IndiaSchool of Applied Sciences, Centurion University of Technology and Management, Odisha, IndiaCTIEMT, Department of Applied Sciences, CT Group of Institutions, Jalandhar, Punjab, IndiaKey Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environment and Materials, Guangxi University, Nanning, ChinaSmart Materials, NanoSYD, Mads Clausen Institute, University of Southern Denmark, Alsion 2, Sønderborg, 6400, DenmarkDepartment of Applied Sciences, Chandigarh Group of Colleges, Jhanjeri, Mohali, Punjab, IndiaKey Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environment and Materials, Guangxi University, Nanning, China; Centre for New Materials and Surface Engineering, NMAMIT, Nitte (Deemed to be university), Nitte, 574110, Karnataka, India; Corresponding author. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environment and Materials, Guangxi University, Nanning, China.Department of Physics, National Institute of Technology Srinagar, Jammu and Kashmir, 190006, India; Corresponding author.Smart Materials, NanoSYD, Mads Clausen Institute, University of Southern Denmark, Alsion 2, Sønderborg, 6400, Denmark; Corresponding author.Polyanion-based materials are considered one of the most attractive and promising cathode materials for lithium-ion batteries (LIBs) due to their good stability, safety, cost-effectiveness, suitable voltages, and minimal environmental impact. However, these materials suffer from poor rate capability and low-temperature performance owing to limited electronic and ionic conductivity, which restricts their practical applicability. Recent developments, such as coating material particles with carbon or a conductive polymer, crystal deformation through the doping of foreign metal ions, and the production of nanostructured materials, have significantly enhanced the electrochemical performances of these materials. The successful applications of polyanion-based materials, especially in lithium-ion batteries, have been extensively reported. This comprehensive review discusses the current progress in crystal deformation in polyanion-based cathode materials, including phosphates, fluorophosphates, pyrophosphates, borates, silicates, sulfates, fluorosilicates, and oxalates. Therefore, this review provides detailed discussions on their synthesis strategies, electrochemical performance, and the doping of various ions.http://www.sciencedirect.com/science/article/pii/S2589965124000047Crystal deformation in polyanionsMetal ions dopingCathode materialsSurface modificationLithium-ion batteries |
| spellingShingle | Sajeela Awasthi Srikanta Moharana Vaneet Kumar Nannan Wang Elham Chmanehpour Anupam Deep Sharma Santosh K. Tiwari Vijay Kumar Yogendra Kumar Mishra Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries Nano Materials Science Crystal deformation in polyanions Metal ions doping Cathode materials Surface modification Lithium-ion batteries |
| title | Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries |
| title_full | Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries |
| title_fullStr | Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries |
| title_full_unstemmed | Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries |
| title_short | Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries |
| title_sort | progress in doping and crystal deformation for polyanions cathode based lithium ion batteries |
| topic | Crystal deformation in polyanions Metal ions doping Cathode materials Surface modification Lithium-ion batteries |
| url | http://www.sciencedirect.com/science/article/pii/S2589965124000047 |
| work_keys_str_mv | AT sajeelaawasthi progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT srikantamoharana progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT vaneetkumar progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT nannanwang progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT elhamchmanehpour progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT anupamdeepsharma progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT santoshktiwari progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT vijaykumar progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries AT yogendrakumarmishra progressindopingandcrystaldeformationforpolyanionscathodebasedlithiumionbatteries |