A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations

A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations

A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectroelectrochemistry studies revealed that the central ligand sustained four reversible redox events, leading to different species with diverse optical behavio...

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Bibliographic Details
Main Authors: Aristide Colin, Yiting Wang, François Lambert, Nathalie Bridonneau, Nicolas Suaud, Régis Guillot, Eric Rivière, Zakaria Halime, Nathalie Guihéry, Shin-ichi Ohkoshi, Talal Mallah
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Magnetochemistry
Subjects:
hexahydroxytriphenylene
non-innocent bridge
trinuclear Co complex
spectroelectrochemistry
Co magnetism
ab initio calculations
Online Access:https://www.mdpi.com/2312-7481/10/12/102
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