Post‐Polymerization Strategy via Dual Site Clicking for Synthesizing Intrinsically Cross‐Linkable Semiconducting Polymers

Post‐Polymerization Strategy via Dual Site Clicking for Synthesizing Intrinsically Cross‐Linkable Semiconducting Polymers

ABSTRACT Crosslinked organic semiconductors have opened the way for various fabrication techniques in the field of organic electronics owing to their three‐dimensional network structure with high solvent resistivity. However, recent efforts to synthesize cross‐linkable semiconducting polymers have b...

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Main Authors: Jaehoon Lee, Seungju Kang, Eunsoo Lee, Jiyun Lee, Tae Woong Yoon, Min‐Jae Kim, Yongjoon Cho, Mingfei Xiao, Yorrick Boeije, Wenjin Zhu, Changduk Yang, Jin‐Wook Lee, Sungjoo Lee, Guobing Zhang, Henning Sirringhaus, Boseok Kang
Format: Article
Language:English
Published: Wiley 2025-01-01
Series:EcoMat
Subjects:
click chemistry
crosslinking
organic semiconductor
post‐polymerization chemistry
solvent resistance
transistor array
Online Access:https://doi.org/10.1002/eom2.12513
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Summary:ABSTRACT Crosslinked organic semiconductors have opened the way for various fabrication techniques in the field of organic electronics owing to their three‐dimensional network structure with high solvent resistivity. However, recent efforts to synthesize cross‐linkable semiconducting polymers have been limited by their low molecular weights and yields. In this study, this limitation is overcome by a novel post‐polymerization strategy. A reagent with a cross‐linkable functional group, (3‐mercaptopropyl)trimethoxysilane, is attached to a diketopyrrolopyrrole‐based donor–acceptor copolymer (DPPTT) via thioesterification and para‐fluoro‐thiol reaction, modifying two sites simultaneously. This modification preserves the molecular weight and electrical properties of the original polymers. In addition, the use of click chemistry enables high yield (98%) without any purification. The modified DPPTT demonstrated high resistance to organic solvents (80% retention dipped in 1‐chlorobenzene for 1 h). Exploiting this benefit, an ultrathin flexible array of 100 organic field‐effect transistors fabricated using conventional photolithography showed high‐performance reliability. Thus, this study provides a universal strategy to synthesize versatile polymer semiconductors for practical organic electronics.
ISSN:2567-3173

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