Photochemical Hydroxyl Group Abstraction from <i>N</i>-Hydroxypyridine-2(1<i>H</i>)-thione Isolated in a Solid Hydrogen Matrix: Photogeneration of 2-Mercaptopyridine

Photochemical Hydroxyl Group Abstraction from <i>N</i>-Hydroxypyridine-2(1<i>H</i>)-thione Isolated in a Solid Hydrogen Matrix: Photogeneration of 2-Mercaptopyridine

Monomers of <i>N</i>-hydroxypyridine-2(1<i>H</i>)-thione were isolated in low-temperature matrices of solid normal hydrogen (n-H<sub>2</sub>). The matrix-isolated compound was irradiated with UV-B (λ = 305 nm) or UV-A (λ > 360 nm) light. Upon such irradiation,...

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Bibliographic Details
Main Authors: Hanna Rostkowska, Maciej J. Nowak, Igor Reva, Leszek Lapinski
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Molecules
Subjects:
photochemistry
IR spectra
hydroxyl radical
2-mercaptopyridine-<i>N</i>-oxide
cage effect
reactive matrix
Online Access:https://www.mdpi.com/1420-3049/29/22/5472
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