Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites
In the present investigation, bio-inorganic composites composed of nano-hydroxyapatite (n-HAp) with chitin and chitosan have been prepared and used for the removal of chromium(VI) ions from aqueous solution. Such composites exhibited a higher Cr(VI) ion sorption capacity than the individual componen...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2010-01-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263-6174.28.1.49 |
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| author | G.N. Kousalya M. Rajiv Gandhi S. Meenakshi |
| author_facet | G.N. Kousalya M. Rajiv Gandhi S. Meenakshi |
| author_sort | G.N. Kousalya |
| collection | DOAJ |
| description | In the present investigation, bio-inorganic composites composed of nano-hydroxyapatite (n-HAp) with chitin and chitosan have been prepared and used for the removal of chromium(VI) ions from aqueous solution. Such composites exhibited a higher Cr(VI) ion sorption capacity than the individual components. The sorption capacities of n-HAp, n-HAp/chitin (n-HApC) composite and n-HAp/chitosan (n-HApCs) composite were found to be 2720, 2845 and 3450 mg/kg, respectively. Batch adsorption studies were conducted to optimize various equilibrating conditions such as the contact time, pH and co-ions. The sorbents were characterized by FT-IR spectroscopy, BET and EDXA analysis. The sorption process could be fitted by both the Freundlich and Langmuir isotherm models. Standard thermodynamic parameters such as the Gibbs' free energy change, ΔG 0 , the standard enthalpy change, ΔH 0 , and the standard entropy change, ΔS 0 , were calculated in order to obtain an understanding of the nature of the sorption process. The kinetics of the reaction could be fitted by the pseudo-second-order and intra-particle diffusion models. The mechanism for Cr(VI) ion sorption onto the composites was established. |
| format | Article |
| id | doaj-art-9e380dffffea48a8afd333aeb352b375 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-9e380dffffea48a8afd333aeb352b3752025-01-02T22:37:33ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382010-01-012810.1260/0263-6174.28.1.49Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid CompositesG.N. Kousalya0M. Rajiv Gandhi1S. Meenakshi2 Department of Chemistry, GTN Arts College, Dindigul-624 005, Tamilnadu, India Department of Chemistry, Gandhigram Rural University, Gandhigram-624 302, Tamilnadu, India Department of Chemistry, Gandhigram Rural University, Gandhigram-624 302, Tamilnadu, IndiaIn the present investigation, bio-inorganic composites composed of nano-hydroxyapatite (n-HAp) with chitin and chitosan have been prepared and used for the removal of chromium(VI) ions from aqueous solution. Such composites exhibited a higher Cr(VI) ion sorption capacity than the individual components. The sorption capacities of n-HAp, n-HAp/chitin (n-HApC) composite and n-HAp/chitosan (n-HApCs) composite were found to be 2720, 2845 and 3450 mg/kg, respectively. Batch adsorption studies were conducted to optimize various equilibrating conditions such as the contact time, pH and co-ions. The sorbents were characterized by FT-IR spectroscopy, BET and EDXA analysis. The sorption process could be fitted by both the Freundlich and Langmuir isotherm models. Standard thermodynamic parameters such as the Gibbs' free energy change, ΔG 0 , the standard enthalpy change, ΔH 0 , and the standard entropy change, ΔS 0 , were calculated in order to obtain an understanding of the nature of the sorption process. The kinetics of the reaction could be fitted by the pseudo-second-order and intra-particle diffusion models. The mechanism for Cr(VI) ion sorption onto the composites was established.https://doi.org/10.1260/0263-6174.28.1.49 |
| spellingShingle | G.N. Kousalya M. Rajiv Gandhi S. Meenakshi Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites Adsorption Science & Technology |
| title | Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites |
| title_full | Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites |
| title_fullStr | Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites |
| title_full_unstemmed | Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites |
| title_short | Removal of Toxic Cr(VI) Ions from Aqueous Solution Using Nano-Hydroxyapatite-Based Chitin and Chitosan Hybrid Composites |
| title_sort | removal of toxic cr vi ions from aqueous solution using nano hydroxyapatite based chitin and chitosan hybrid composites |
| url | https://doi.org/10.1260/0263-6174.28.1.49 |
| work_keys_str_mv | AT gnkousalya removaloftoxiccrviionsfromaqueoussolutionusingnanohydroxyapatitebasedchitinandchitosanhybridcomposites AT mrajivgandhi removaloftoxiccrviionsfromaqueoussolutionusingnanohydroxyapatitebasedchitinandchitosanhybridcomposites AT smeenakshi removaloftoxiccrviionsfromaqueoussolutionusingnanohydroxyapatitebasedchitinandchitosanhybridcomposites |